STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP

CHEN Shuang-ji; LI Fu-mian

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STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP

Research Bulletin | 更新时间：2021-03-19

- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP
- Acta Polymerica Sinica Issue 5, Pages: 628-632(1989)
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- Published：20 October 1989，
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CHEN Shuang-ji, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP. [J]. Acta Polymerica Sinica (5):628-632(1989)
DOI：

CHEN Shuang-ji, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP. [J]. Acta Polymerica Sinica (5):628-632(1989) DOI：

摘要

Abstract

The photopolymerization of AN by using N-acryloyl-N'-phenylpiperazine (APP) and N-methacryloyl-N'-phenylpiperazine (MPP) as sensitizers under UV irradiation has been investigated. The corresponding polymerization kinetic equations are as follows:Rp [APP]0.81[AN]0.61 Rp [MPP]0.48[AN]0.77 Rp [P(APP)]0.53[AN]0.78 From the fluorescent analysis

it was confirmed that APP

MPP and P(APP) not only initiated the polymerization of AN but also entered into the chains of AN polymer. The photopolymerization mechanism for exciplex formation of AN with above sensitizers was proposed.

关键词

N-丙烯酰-N′-苯基哌嗪N-甲基丙烯酰-N′-苯基哌嗪含胺基功能性单体光聚合丙烯腈荧光

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