LAI CHU-GEN, LU JIA-LIN, FANG YAO-REN, BAO FI-YI. THE KINETICS OF POLYESTERIFICATION, ESTERIFICATION, AND HYDROLYSIS OF ESTER. [J]. Acta Polymerica Sinica 7(6):373-385(1965)
DOI:
LAI CHU-GEN, LU JIA-LIN, FANG YAO-REN, BAO FI-YI. THE KINETICS OF POLYESTERIFICATION, ESTERIFICATION, AND HYDROLYSIS OF ESTER. [J]. Acta Polymerica Sinica 7(6):373-385(1965)DOI:
THE KINETICS OF POLYESTERIFICATION, ESTERIFICATION, AND HYDROLYSIS OF ESTER
the action of alcohol as a carrier of H+-ion was supposed to be negligable
in contrast to the result obtained by Tang Au-Ching. A new hypothesis of polyesterification was then suggested.This mechanism can be used to explain some other types of esterification as well. Favourable results were obtained even if p (the percent of the theoretical degree of reaction) is greater than 91%. In the hydrolysis of esters by using strong or weak acid as catalysts
results obtained were found to be better than those obtained by previous authors.