ISOTHERMAL COMPRESSION BEHAVIOUR OF POLYMER SOLIDS UP TO 3 Gpa
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Research Article|更新时间:2021-03-19
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ISOTHERMAL COMPRESSION BEHAVIOUR OF POLYMER SOLIDS UP TO 3 Gpa
Acta Polymerica SinicaIssue 1, Pages: 86-92(1989)
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Published:20 February 1989,
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YANG Mei-lin, SHEN Jia-cong, CUI Qi, liang. ISOTHERMAL COMPRESSION BEHAVIOUR OF POLYMER SOLIDS UP TO 3 Gpa. [J]. Acta Polymerica Sinica (1):86-92(1989)
DOI:
YANG Mei-lin, SHEN Jia-cong, CUI Qi, liang. ISOTHERMAL COMPRESSION BEHAVIOUR OF POLYMER SOLIDS UP TO 3 Gpa. [J]. Acta Polymerica Sinica (1):86-92(1989)DOI:
ISOTHERMAL COMPRESSION BEHAVIOUR OF POLYMER SOLIDS UP TO 3 Gpa
The applicabilities of Tait and Murnaghan equations of state and Bridgman polynomial to isothermal compressions of 10 polymer solids have been examined up to 3 GPa at room temperature. Tait and Murnaghan equations are equivalent and their linear forms (6) and (7) are very accurately for multisegmentally fitting the isothermal P-V date of amorphous
semi-crystaline polymer solids with the universal values CT= 0.0894 for Tait and CM= 0.1016 for Murnaghan parameter
Bridgman polynomial can also be used but is inconvenient when there are pressure-induced transitions. Equation is also presented for Gruneisen parameter from Tait and Murna-ghan parameters.