STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers

LI Fu-mian; WANG Lin; DING Yi-wei; FENG Xin-de

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STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers

Research Bulletin | 更新时间：2021-03-19

- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers
- Acta Polymerica Sinica Issue 4, Pages: 316-320(1985)
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- Published：20 August 1985，
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LI Fu-mian, WANG Lin, DING Yi-wei, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers. [J]. Acta Polymerica Sinica (4):316-320(1985)
DOI：

LI Fu-mian, WANG Lin, DING Yi-wei, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers. [J]. Acta Polymerica Sinica (4):316-320(1985) DOI：

摘要

Abstract

Aliphatie tertiary amino-group N-substituted aerylamides．N-acrylyLN’-methylpipe-rasine (AMP) and N-methaerylyl-N'-methyl piperazine(MAMP) were synthesized dire-ctly．from N-methylpiperasine with corresponding acryl chlorides and characterized bly the elementary analysis of their picrates，1H-NMR

IRand MS. AMP did not poly-merize with benzoyl peroxide．but could polymerize with LPO．The rate equation of the polymerization was given as Rp=Kp [AMP]0.5 [LPO]0.5 and the overall activation energy of this polymerization system was determined as low as 10.8 keal／mol．The redox nature of LPO with the monomer itself had been suggested．The polymers of these N-substituted aerylamides display good antithrombogeneeity tested by reaeleifieation me-thod.

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