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Published:20 February 1979,
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Lo Chang-pin, Ko Li-fen. HYDROLYSIS OF POLYACRYLONITRILE UNDER PRESSURE. [J]. Acta Polymerica Sinica (1):31-35(1979)
DOI:
Lo Chang-pin, Ko Li-fen. HYDROLYSIS OF POLYACRYLONITRILE UNDER PRESSURE. [J]. Acta Polymerica Sinica (1):31-35(1979) DOI:
定型纤维状或无定型的聚丙烯腈在高温压力下均可用水水解
且产物中含有酰胺、酰亚胺、羧酸铵盐
经减压干燥后
铵盐部分分解成羧酸
最后的平均相对组成为:羧酸∶铵盐∶酰胺∶酰亚胺≈13∶36∶18∶33。 在我们的反应条件下
聚丙烯腈产生严重的断链现象
分子量大为降低
特别是未经喷丝成型的浆块更严重。 用阳离子交换树脂交换之后再进行分析的方法
一方面避免了滴定两种不同羧基(游离羧基、铵盐的羧基)之间的干扰
同时亦避免了通常方法测定铵盐时酰胺的干扰
因而数据更为可靠。
Hydrolysis of polyacrylonitrile fibers under pressure (15 atm.) at 180-185° C by water gave a copolymer of acrylamide
acrylimide and the ammonium salt of acrylic acid and their homopolymers. The ammonium salt of polyacrylie acid after being dried
was partially decomposed into polyacrylie acid and ammonia. The final product consists of polyacrylie acid
its ammonium salt
polyacrylamide and polyacrylimide in the ratio of ca 13:36:18:33.
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