The thermodynamic parameters of fusion of polyepichlorohydrin were investigated by Flory's method based on the melting point decrease for polymer diluent mixtures. Toluene

α-chloronahthalene and nitrobenzene were used as diluents.The equilibrium melting temperature was obtained by extrapolating the "kinetic" melting points

measured on polymers crystallized at various temperatures.The equilibrium melting temperature

fusion enthalpy and fusion entropy obtained are 116℃

10.6 KJ/mol asd 27.2 J/mol. K resp.