CHARGE TRANSFER PHENOMENON BETWEEN C60AND PARA-N,N-DIMETHYLAMINOSTYRENE AND ITS POLYMER

QIU Jian; YIN Qian; YANG Huaquan; YAO Guangqing; LI Fumian

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CHARGE TRANSFER PHENOMENON BETWEEN C60AND PARA-N,N-DIMETHYLAMINOSTYRENE AND ITS POLYMER

Research Bulletin | 更新时间：2021-03-19

- CHARGE TRANSFER PHENOMENON BETWEEN C60AND PARA-N,N-DIMETHYLAMINOSTYRENE AND ITS POLYMER
- Acta Polymerica Sinica Issue 5, Pages: 608-611(1996)
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- Published：20 October 1996，
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QIU Jian, YIN Qian, YANG Huaquan, YAO Guangqing, LI Fumian. CHARGE TRANSFER PHENOMENON BETWEEN C60AND PARA-N,N-DIMETHYLAMINOSTYRENE AND ITS POLYMER. [J]. Acta Polymerica Sinica (5):608-611(1996)
DOI：

QIU Jian, YIN Qian, YANG Huaquan, YAO Guangqing, LI Fumian. CHARGE TRANSFER PHENOMENON BETWEEN C60AND PARA-N,N-DIMETHYLAMINOSTYRENE AND ITS POLYMER. [J]. Acta Polymerica Sinica (5):608-611(1996) DOI：

摘要

对－Ｎ

Ｎ－二甲氨基苯乙烯及其聚合物与碳－６０的电荷转移现象邱健

尹芊

杨华铨

姚光庆

李福绵（北京大学化学系北京１００８７１）关键词电荷转移复合物

对－Ｎ

Ｎ－二甲氨基苯乙烯

碳－６０

荧光光谱电荷转移现象是备受瞩目的一个研究领域

诸如在电荷转移引发聚合、导电与超导材料、磁性材料、非线性光学材料等方面都有诱人的应用前景

目前

将电荷转移复合物进行高分子化从而作为功能材料来使用也是一个研究热?...

Abstract

P-N

N-Dimethylaminostyrene (DMAS) was synthesized through Wittigreaction and polymerized using AIBN as an initiator．The charge transfer complexformed between monomeric and polymeric DMAS with electron acceptors such asunsaturated nitriles and acrylates as well as C60 Was verified by fluorescence method．A distinct curvature appearing in the Stern-Volmer plot of P (DMAS) quenched by(C60 proved that the CTC was formed in the ground state．The measurement of oxidation-reduction potential and fluorescence behavior of monomeric and polymeric DMASwould contribute to the conformation of monomer and polymer in solution．

关键词

电荷转移复合物对－ＮＮ－二甲氨基苯乙烯碳－６０荧光光谱

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