SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX

CHEN Yuan-yin; LU Xue-ran; CAI Ming-zhong

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SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX

Research Bulletin | 更新时间：2021-03-19

- SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX
- Acta Polymerica Sinica Issue 4, Pages: 489-491(1990)
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- Published：20 August 1990，
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CHEN Yuan-yin, LU Xue-ran, CAI Ming-zhong. SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX. [J]. Acta Polymerica Sinica (4):489-491(1990)
DOI：

CHEN Yuan-yin, LU Xue-ran, CAI Ming-zhong. SYNTHESIS AND CATALYTIC CHARACTERISTICS OF POL YSILOXANE-SUPPORTED THIIRANE PLATINUM COMPLEX. [J]. Acta Polymerica Sinica (4):489-491(1990) DOI：

摘要

Abstract

Fumed silica-bound poly-4-oxa-6

7-epithioheptylsiloxane platinum complex was synthesized from γ-(2

3-epithiopropoxy) propyltrimethoxysilane via immobilization on fumed silica

followed by reacting with potassium chloroplatinite in acetone. It was found that the title complex exhibits high catalytic activity for the hydrosilylation of olefins by triethoxysilane and excellent recovery and reuse properties. The yield of decyltriethoxysilane was unchanged from the second run to fifteenth run.

关键词

环硫乙烷铂配合物硅氢加成硅氢加成催化剂有机硅聚合物负载催化剂

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