STUDY OF KINETICS OF POLYMERIZATION OF PROPYLENE BY SOLVAY CATALYST

Zhang Cui-ju; Yu Xun

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STUDY OF KINETICS OF POLYMERIZATION OF PROPYLENE BY SOLVAY CATALYST

Research Article | 更新时间：2021-03-19

- STUDY OF KINETICS OF POLYMERIZATION OF PROPYLENE BY SOLVAY CATALYST
- Acta Polymerica Sinica Issue 4, Pages: 214-218(1980)
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- Published：20 August 1980，
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Zhang Cui-ju, Yu Xun. STUDY OF KINETICS OF POLYMERIZATION OF PROPYLENE BY SOLVAY CATALYST. [J]. Acta Polymerica Sinica (4):214-218(1980)
DOI：

Zhang Cui-ju, Yu Xun. STUDY OF KINETICS OF POLYMERIZATION OF PROPYLENE BY SOLVAY CATALYST. [J]. Acta Polymerica Sinica (4):214-218(1980) DOI：

摘要

用封闭和开放体系测定了索尔维(Solvay)型催化剂-AlEt_2Cl体系丙烯聚合时温度对聚合速度的影响

测定了反应级数和速度常数

采用下式: E=2.303R log(K2/K1)[(T1·T2)/(T2-T1)] E=2.303R log(V2/V1)[(T1·T2)/(T2-T1)]分别求得了活化能。

Abstract

The effects of temperature on polymerization rate of propyleno were determined with diethyl aluminum chloride catalyst system in both open and closed operation systems. The order and the rate constant of the reaction were determined. The energy of activation is calculated from the following eguations:

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