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Published:20 December 1990,
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MO Zhi-shen, ZHANG Hong-fang, MENG Qing-bo, XUE Xiao-fu, ZHANG Li-hua. CRYSTAL STRUCTURE OF NYLON-1010. [J]. Acta Polymerica Sinica (6):655-660(1990)
DOI:
MO Zhi-shen, ZHANG Hong-fang, MENG Qing-bo, XUE Xiao-fu, ZHANG Li-hua. CRYSTAL STRUCTURE OF NYLON-1010. [J]. Acta Polymerica Sinica (6):655-660(1990) DOI:
用WAXD方法测定了Nylon-1010为三斜晶系结晶结构;α=4.9A
b=5.4A
c=27.8(?)
α=49°
β=77°
γ=63.5°
每个聚合物单胞含有一个重复单元
空间群为PA。模压试样用Ruland方法分析结晶度为60%。以上。电子密度相关函数法分析了SAXS现象
求得了Nylon-1010结晶片层厚度、过渡层厚度、长周期、比内表面及电子密度差。
From X-ray diffraction patterns of uniaxially oriented fibers
the crystal structure of Nylon-1010 was determined. The Nylon-1010 crystallizes in the triclinic system
with lattice dimensions: a = 4.9A
b = 5Ak
c = 27.8A
α = 49°
β = 77°
γ= 63.5°
the unit cell contains one monomeric unit and the space group is PI. The degree of crystallinity of polymer was determined as about 60%
using Ruland's method.SAXS has been used to investigate the crystalline lamellar thickness
long periods
transition zones
the specific inner surface andan electron density difference between the crystal-line and amorphous regions for Nylon-1010
the analysis of data was based upon the one-dim-ensional electrondensity correlation function (EDCF).
尼龙-1010结晶结构广角X射线衍射小角X射线散射电子密度相关函数中间相
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