CATALYSIS OF PALLADIUM SUPPORTED ON CHELATE RESIN WITH 8-AMINOQUINOLINE FOR HYDROGENATIONS OF OLEFINS

HE Bing-lin; WANG Li

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CATALYSIS OF PALLADIUM SUPPORTED ON CHELATE RESIN WITH 8-AMINOQUINOLINE FOR HYDROGENATIONS OF OLEFINS

Research Article | 更新时间：2021-03-19

- CATALYSIS OF PALLADIUM SUPPORTED ON CHELATE RESIN WITH 8-AMINOQUINOLINE FOR HYDROGENATIONS OF OLEFINS
- Acta Polymerica Sinica Issue 5, Pages: 404-408(1987)
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- Published：20 October 1987，
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HE Bing-lin, WANG Li. CATALYSIS OF PALLADIUM SUPPORTED ON CHELATE RESIN WITH 8-AMINOQUINOLINE FOR HYDROGENATIONS OF OLEFINS. [J]. Acta Polymerica Sinica (5):404-408(1987)
DOI：

HE Bing-lin, WANG Li. CATALYSIS OF PALLADIUM SUPPORTED ON CHELATE RESIN WITH 8-AMINOQUINOLINE FOR HYDROGENATIONS OF OLEFINS. [J]. Acta Polymerica Sinica (5):404-408(1987) DOI：

摘要

本文在带有8-氨基喹啉螯合基团的树脂上负载了二氯化钯

再经甲醇-水还原合成混合价态钯催化剂。考察并比较了两类催化剂的加氢活性及选择性

发现混合价态钯催化剂具有活性高、选择性强、金属不易流失的特点。

Abstract

A polymer-bound palladium (II) chloride complex has been prepared by the reaction of palladium chloride with a chelate resin of 8-aminoquinoline. Refluxing the complex in methanol-water solution

it gives a polymer-bound mixed valence palladium catalyst. The activity and selectivity for hydrogenation of the olefins with the above catalyst have been studied. It was found that the polymer-bound mixed valence palladium catalyst is more active and selective for hydro-genations of olefins. The catalvst is also stable. There is no obvious loss of palladium of the catalyst.

关键词

钯催化剂加氢催化剂寿命环十二碳三烯混合价态

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