QIU Kun-yuan, SONG Ye. GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY (N-PARA-TOLYLACRYLAMIDES) FILMS INITIATED BY CERIC ION. [J]. Acta Polymerica Sinica (5):321-326(1987)
DOI:
QIU Kun-yuan, SONG Ye. GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY (N-PARA-TOLYLACRYLAMIDES) FILMS INITIATED BY CERIC ION. [J]. Acta Polymerica Sinica (5):321-326(1987)DOI:
GRAFT COPOLYMERIZATION OF ACRYLAMIDE ONTO POLY (N-PARA-TOLYLACRYLAMIDES) FILMS INITIATED BY CERIC ION
NPMAAM were synthesized. Binary initiation systems consisted of eerie ammonium nitrate (CAN) and these functional monomers could initiate acrylamide (AAM) polymerization. It was found that AAM could graft copoly-merize onto macromolecules having paratolylcarbamoyl and phenylcarbamoyl pendant groups
such as PNTAAM
PNTMAAM
PNPMAAM and copolymers 1-6. The formation of graft copolymer has been verified by its water absorption %
contact angle with water
the X-ray pho-toelectron spectrometry and the scanning electron microscopy hotographs. The reaction mecha-nism was proposed and the main reactive site of graft copolymerization initiated by ceric ion would take place predominantly at the functional pednant group.