THE PHOTOPOLYMERIZATION OF METHYL METHACRYLATE INITIATED BY THE PHOTOREDOX SYSTEM CONSISTING OF N-(4-BENZOYLPHENYL) MALEIMIDE AND THE POLYMERIZABLE TERTIARY AMINE

GAO Qingyu; YANG Gengxu; ZHANG Fulian; ZHANG Juxian; LI Fumian

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THE PHOTOPOLYMERIZATION OF METHYL METHACRYLATE INITIATED BY THE PHOTOREDOX SYSTEM CONSISTING OF N-(4-BENZOYLPHENYL) MALEIMIDE AND THE POLYMERIZABLE TERTIARY AMINE

Research Bulletin | 更新时间：2021-03-19

- THE PHOTOPOLYMERIZATION OF METHYL METHACRYLATE INITIATED BY THE PHOTOREDOX SYSTEM CONSISTING OF N-(4-BENZOYLPHENYL) MALEIMIDE AND THE POLYMERIZABLE TERTIARY AMINE
- Acta Polymerica Sinica Issue 3, Pages: 369-373(1996)
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- Published：20 June 1996，
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GAO Qingyu, YANG Gengxu, ZHANG Fulian, ZHANG Juxian, LI Fumian. THE PHOTOPOLYMERIZATION OF METHYL METHACRYLATE INITIATED BY THE PHOTOREDOX SYSTEM CONSISTING OF N-(4-BENZOYLPHENYL) MALEIMIDE AND THE POLYMERIZABLE TERTIARY AMINE. [J]. Acta Polymerica Sinica (3):369-373(1996)
DOI：

GAO Qingyu, YANG Gengxu, ZHANG Fulian, ZHANG Juxian, LI Fumian. THE PHOTOPOLYMERIZATION OF METHYL METHACRYLATE INITIATED BY THE PHOTOREDOX SYSTEM CONSISTING OF N-(4-BENZOYLPHENYL) MALEIMIDE AND THE POLYMERIZABLE TERTIARY AMINE. [J]. Acta Polymerica Sinica (3):369-373(1996) DOI：

摘要

４－Ｎ－二苯甲酮基马来酰亚胺与可聚合脂肪叔胺构成的光氧化还原体系引发甲基丙烯酸甲酯光聚合高青雨

杨更须

张福莲

张举贤（河南大学化学化工系开封４７５００１）李福绵（北京大学化学系北京１００８７１）关键词４－Ｎ－二苯甲酮基马来酰亚胺

甲基丙烯酸－Ｎ

Ｎ－二甲氨基乙酯

可聚合光氧化还原引发体系我们曾报道了可聚合的脂肪叔胺如甲基丙烯酸－Ｎ

Ｎ－二甲氨基乙酯（ＤＭＡＥＭＡ）与药酮．二苯甲酮组成光引发?...

Abstract

Photo-initiation behavior of N-(4-benzoylphenyl)maleindde (NBPMI)

combining with dimethyaminoethyl metharylate (DMAEMA) or its polymer P(DMAEMA) was studied. The photopolymerization rate equations and their overall activation energies were obtained as follows:Rp∝[NBPMI]0.48[DMAEMA]0.18 [MMA]0.82 Ea=26.8 kJ /mol Rp∝[P(NBPMI-DMAEMA)]0.32[MMA]0.92 Ea=21.7 kJ /mol Rp∝[NBPMI]0.38 [P(DMAEMA)]0.65[MMA]0.70 Ea=33.2 kJ /mol The polymeric photoinitiator system shows higher initiation ability than that of the monomericate one. The UV spectrum of P(MMA) initiated by the NBPMI-DMAEMA of MMA

but also enter into P(MMA) polymer chains.

关键词

４－Ｎ－二苯甲酮基马来酰亚胺甲基丙烯酸－ＮＮ－二甲氨基乙酯可聚合光氧化还原引发体系

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