SYNTHESIS AND CROSSLINKING OF LIQUID POLYSILANE POLYMER

ZHANG Xing-hua; ROBERT West

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SYNTHESIS AND CROSSLINKING OF LIQUID POLYSILANE POLYMER

Research Article | 更新时间：2021-03-19

- SYNTHESIS AND CROSSLINKING OF LIQUID POLYSILANE POLYMER
- Acta Polymerica Sinica Issue 4, Pages: 257-263(1986)
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- Published：20 August 1986，
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ZHANG Xing-hua, ROBERT West. SYNTHESIS AND CROSSLINKING OF LIQUID POLYSILANE POLYMER. [J]. Acta Polymerica Sinica (4):257-263(1986)
DOI：

ZHANG Xing-hua, ROBERT West. SYNTHESIS AND CROSSLINKING OF LIQUID POLYSILANE POLYMER. [J]. Acta Polymerica Sinica (4):257-263(1986) DOI：

摘要

采用具有不同有机取代基的二氯硅烷与甲基二苯基氯硅烷为原料

在甲苯中以金属钠共缩合的方法

合成了可流动的聚硅烷。这些聚硅烷可用灌注、浇铸、涂敷等方法制成各种形状

并能在多乙烯基硅烷存在下

以紫外光辐照进行交联。本文还讨论了这些聚硅烷的分子量分布以及红外、紫外、核磁共振等光谱性质。

Abstract

Flowable polysilane polymers have been synthesized by sodium coupling of diorgano-dichlorosilanes with diphenylmethylchlorosilane in toluene. These polysilanes can be formed into desired shape by potting

casting or coating and crosslinked by ultraviolet irradiation in the presence of multifunctional vinylsilanes. The molecular weight distributions

infra-red

ultraviolet and nuclear magnetic resonance spectra for the polysilane polymers have been described.

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