STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides

ZTANG Zhen-yu; ZHOU Hao-ran; WANG Ai-rong; LI Fu-mian

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STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides

Research Bulletin | 更新时间：2021-03-19

- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides
- Acta Polymerica Sinica Issue 2, Pages: 149-152(1987)
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- Published：20 April 1987，
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ZTANG Zhen-yu, ZHOU Hao-ran, WANG Ai-rong, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides. [J]. Acta Polymerica Sinica (2):149-152(1987)
DOI：

ZTANG Zhen-yu, ZHOU Hao-ran, WANG Ai-rong, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides. [J]. Acta Polymerica Sinica (2):149-152(1987) DOI：

摘要

Abstract

Methylene-morpholino-group N-substituted acrylamides

i. e. N-(N'-methylene-morpholino) methacrylamide (MMMA) and N-(N'-methylene-morpholino) acrylamide (MMAA) were syn-thsized and polymerized. It was found that these monomers were hardly polymerized initiated with BPO

but could be polymerized with LPO. The polymerization kinetic equations initiated with LPO were obtained asRp= Kp[MMMP]1.5[LPO]0.5Rp = Kp[ MMAA]1.5[LPO]0.5and the overall activation energies were obtained as low as 13.4 Kcal/mol and 9.2 Kcal/mol respectively. The redox nature of the polymerization of these aliphatic tertiary amino-group N-substituted acrylamides initiated with LPO would be suggested.

关键词

功能性单体氧化还原引发表观活化能N-（N′-次甲基吗啉）甲基丙烯酰胺

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