QI Yin-cheng, WU Guang-ying, LU Ge-jue, WEI Yong-kang. THE KINETICS AND MECHANISM OF ALTERNATING COPOLYMERIZATION OF METHYL ACRYLATE AND ISOBUTYLENE. [J]. Acta Polymerica Sinica (6):707-712(1993)
DOI:
QI Yin-cheng, WU Guang-ying, LU Ge-jue, WEI Yong-kang. THE KINETICS AND MECHANISM OF ALTERNATING COPOLYMERIZATION OF METHYL ACRYLATE AND ISOBUTYLENE. [J]. Acta Polymerica Sinica (6):707-712(1993)DOI:
THE KINETICS AND MECHANISM OF ALTERNATING COPOLYMERIZATION OF METHYL ACRYLATE AND ISOBUTYLENE
The kinetics and mechanism of copolymerization of methyl acrylate (MA) and isobuty-lene (IB) in the presence of AlEtCl2 and benzoyl peroxide (BPO) has been examined. It is suggested that when [IB]≥[MA]
the copolymerization proceeds via a homopolymerization of a three-component complexed monomer (T) to form the alternating MA-IB copolymer. When [MA]>[IB]
the formation of a MA-IB copolymer rich in MA and containing MA blocks may occur through the copolymerization of a three-component complexed monomer (T) and a two-component complexed monomer (B)