SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS

HONG Ren-fang; MITSUO Ishikawa

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SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS

Research Article | 更新时间：2021-03-19

- SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS
- Acta Polymerica Sinica Issue 6, Pages: 667-671(1993)
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- Published：20 December 1993，
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HONG Ren-fang, MITSUO Ishikawa. SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS. [J]. Acta Polymerica Sinica (6):667-671(1993)
DOI：

HONG Ren-fang, MITSUO Ishikawa. SYNTHESIS OF COPOLYMER FROM 1,2-DIETHYNYLTETRA- PHENYIDISILANE AND 1,2-DIETHYNYLTETRAMETHYLDISILANE AND ITS PHOTOLYSIS. [J]. Acta Polymerica Sinica (6):667-671(1993) DOI：

摘要

2-二乙炔基四苯基乙硅烷与1

2-二乙炔基四甲基乙硅烷在催化剂铑(Ⅰ)络合物[氯化三-(三苯基膦)铑]的作用下得到一种新的含硅共聚物。实验证明此共聚物的主链是有规交替结构。研究了固体薄膜及其溶液的光解作用

并测定了SbF5蒸气处理后的共聚物薄膜的导电性。

Abstract

A new copolymer was synthesized by 1

2-diethynyltetraphenyldisilane and 1

2-di-ethynyltetramethyldisilane with a catalytic amount of a rhodium ( I ) complex. We have found that this copolymer has regular alternating arrangement in the copolymer backbone. The photochemical behavior has been examined in solid film and in solution of the copolymer. The film was treated with SbF5 vapour. And its conductivity was measured.

关键词

共聚物结构光解导电性

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