WANG Hong-zuo, LIAO Dong-sheng, WANG Ying. STUDIES ON THE POLYMERIZATION OF MMA INITIATED BY THE Cu(Ⅱ)IONOMERS BASED ON ITACONATE. [J]. Acta Polymerica Sinica (6):641-647(1993)
DOI:
WANG Hong-zuo, LIAO Dong-sheng, WANG Ying. STUDIES ON THE POLYMERIZATION OF MMA INITIATED BY THE Cu(Ⅱ)IONOMERS BASED ON ITACONATE. [J]. Acta Polymerica Sinica (6):641-647(1993)DOI:
STUDIES ON THE POLYMERIZATION OF MMA INITIATED BY THE Cu(Ⅱ)IONOMERS BASED ON ITACONATE
The Cu (Ⅱ)-ionomers based on itaconate can initiate the polymerization of MMA in the presence of CC14. Its free radical polymerization mechanism was demonstrated and the effects of various reaction conditions on the rate of polymerization
conversion and molecular weight were studied. The kinetic equation of polymerization can be expressed as Rp = Ke-67235/RT (Ionomer)0.04 (MMA)1.34(CCl4)m (in this experiment m=0. 5-3)