LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE

ZHANG Sheng-shui; WAN Guo-xiang

doi:null

您当前的位置：

首页 >

文章列表页 >

LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE

Research Article | 更新时间：2021-03-19

- LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE
- Acta Polymerica Sinica Issue 1, Pages: 42-46(1993)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：20 February 1993，
扫描看全文
ZHANG Sheng-shui, WAN Guo-xiang. LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE. [J]. Acta Polymerica Sinica (1):42-46(1993)
DOI：

ZHANG Sheng-shui, WAN Guo-xiang. LITHIUM-IONIC CONDUCTION IN THE BLEND OF THE COMB-LIKE POLYETHER WITH LITHIUM POLYSULFONATE. [J]. Acta Polymerica Sinica (1):42-46(1993) DOI：

摘要

本工作合成了聚甲基丙烯酸齐聚氧化乙烯酯和聚甲基丙烯酸己磺酸锂两系列聚合物

研究共聚物结构对共混物的相容性和锂离子导电性的影响.结果表明

共混物的相容性是决定离子电导率的主要因素;共混物内锂离子传导发生在非晶区

聚合物的链段运动是离子传导的主要推动力.

Abstract

Poly foligo(oxyethylene) methacrylate] and poly(methacryloyl hexylsulfonic acid lithium) were successfully synthesized

from which the blends with single-Li+-ionic conduction were prepared. The Li+-ionic conductivity was deeply influenced by the compatibility

composition and temperature of the blends. The results show that the better the compatibility of the blends

the higher the conductivity. Li+Monic migration in the blend occurs mainly in amorphour regions and accelerates with increasing segmental motion of the matrix polymers. An optimum Li+-ionic conductivity of 5.3×10-7S/cm at 25℃ was observed for the homogeneous blend PMEO18/P(0.5SHMLi-0.5HEMA) with O/L:=70.

关键词

高分子固体电解质共混物锂离子导体相容性

Keywords

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

STUDIES ON CRYSTALLIZATION BEHAVIOR AND COMPATIBILITY OF POLY(ETHYLENE OXIDE)(PEO)/ POLY(2 ETHYL 2 OXAZOLINE)(PEOx) Blends

STUDY ON THE CRYSTALLINE PHASE COMPATIBILITY OF POLYMERS

POLY(3-HYDROXYBURATE)/POLY(HYDRO ETHER OF BISPHENOL A) BLENDS:PHASE STRUCTURE AND MISCIBILITY

STUDIES ON IONOMERS AND THE RELATED BLENDS─2.COMPATIBILIZATION BASED ON COORDINATE COMPLEXATION AND PROTON-TRANSFER

STUDIES ON IONOMERS AND THE RELATED BLENDS Ⅰ.Compatibilization by Introducing Like Ions into Component Polymers

Related Author

No data

Related Institution

No data

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰