Four new acrylate terpolymer supported sulfide platinum complexes were synthesized by copolymerization of 1
4-butanediol diaorylate
methyl acrylate
β-chloroethyl acrylate of ω-chlorohexyl acrylate in various molar ratio
followed by mercaptoethylation with sodium ethyl mercaptide
and by reaction with K2PtCl4. Decene-1
dodecene-1
allyl phenyl ether and sty-rene were used as probe to explore their catalytic characteristics in the hydrosilylation reaction. The influences of temperature
the amount of complex used on the catalytic activity and reused properties were also investigated.
SYNTHESIS OF POLY-4,7-DITHIANONYLSILSESQUIOXANE RHODIUM COMPLEX AND ITS CATALYTIC BEHAVIOR FOR THE HYDROSILYLATION OF OLEFINS WITH TRIETHOXYSILANE
SYNTHESIS OF POLY(4-OXA-6,7-DIMETHYLMERCAPTOHEP- TYL) SILOXANE PLATINUM COMPLEX AND ITS CATALYTIC ACTIVITY FOR THE HYDRO- SILYLATION OF OLEFINS
CATALYTIC CHARACTERISTICS OF POLY-y-(m-DIPHENYLP- HOSPHINOPHENYL) PROPYLSILOXANE PLATINUM COMPLEX FOR THE HYDROSILYLATION OF OLEFINS WITH TRIMETHOXYSILANE