Toward Correct Measurements of Shear Rheometry

Shuang Liu; Xiao Cao; Jia-qi Zhang; Ying-chun Han; Xin-yue Zhao; Quan Chen

doi:10.11777/j.issn1000-3304.2020.20230

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Toward Correct Measurements of Shear Rheometry

Reviews | 更新时间：2021-03-05

- Toward Correct Measurements of Shear Rheometry
- Acta Polymerica Sinica Vol. 52, Issue 4, Pages: 406-422(2021)
- 作者机构：
  
  1.中国科学院长春应用化学研究所高分子物理与化学国家重点实验室　长春 130022
  2.中国科学技术大学应用化学与工程学院　合肥 230026
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2020.20230
  CLC：
- Published：3 April 2021，
  
  Published Online：8 January 2021，
  
  Received：14 October 2020，
  
  Revised：3 December 2020，
扫描看全文
Shuang Liu, Xiao Cao, Jia-qi Zhang, Ying-chun Han, Xin-yue Zhao, Quan Chen. Toward Correct Measurements of Shear Rheometry. [J]. Acta Polymerica Sinica 52(4):406-422(2021)
DOI：

Shuang Liu, Xiao Cao, Jia-qi Zhang, Ying-chun Han, Xin-yue Zhao, Quan Chen. Toward Correct Measurements of Shear Rheometry. [J]. Acta Polymerica Sinica 52(4):406-422(2021) DOI： 10.11777/j.issn1000-3304.2020.20230.

摘要

流变学是高分子加工和应用的重要基础，流变学表征对于深入理解高分子流动行为非常重要，获取的流变参数可用于指导高分子加工. 本文首先总结了剪切流变测试中的基本假设：(1)设置的应变施加在样品上，(2)应力来源于样品自身的响应和(3)施加的流场为纯粹的剪切流场；之后具体阐述了这些假设失效的情形和所导致的常见的实验错误；最后，通过结合一些实验实例具体说明如何培养良好的测试习惯和获得可靠的测试结果.

Abstract

Rheology is an important tool for characterizing polymeric materials. The knowledge of polymer dynamics obtained from rheological measurements can guide the processing of polymeric materials. Nevertheless

it is a challenging task to conduct precise measurements on shear rheometers. First

we summarize the basic assumptions of rheological measurements: (1) the applied strain is on the sample

(2) the stress reflects sample’s own stress response

and (3) the flow field is purely the shear flow. Second

we highlight the conditions under which the above assumptions become invalid

which leads to incorrect measurements. For example

the first assumption is violated when compliance of the equipment or the wall-slip becomes non-negligible

the second assumption is violated when either inertia of the equipment

that of the sample

or the interfacial tension contributes non-negligibly to the overall torque

and the third assumption is violated when there is the secondary flow

shear-banding

or edge fracture. We show some examples of the incorrect measurements owing to these violations of the assumptions. Finally

we stress the importance of good experimental practice in rheological experiments.

关键词

流变学剪切流场剪切流变测试

Keywords

RheologyShear flow fieldShear rheology measurement

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State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute, Sichuan University

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