Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films

Meng-yan Gao; Chang-ou Wang; Yan Jia; Lei Zhai; Song Mo; Min-hui He; Lin Fan

doi:10.11777/j.issn1000-3304.2021.21094

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Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films

Review | 更新时间：2023-12-20

- Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films
- ACTA POLYMERICA SINICA Vol. 52, Issue 10, Pages: 1283-1297(2021)
- 作者机构：
  
  1.中国科学院化学研究所极端环境高分子材料重点实验室北京 100190
  2.中国科学院大学化学科学学院北京 100049
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21094
  CLC：
- Published：20 October 2021，
  
  Published Online：04 August 2021，
  
  Received：24 March 2021，
  
  Revised：09 April 2021，
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高梦岩,王畅鸥,贾妍等.聚酰亚胺薄膜材料的各向异性导热行为研究与进展[J].高分子学报,2021,52(10):1283-1297.

Gao Meng-yan,Wang Chang-ou,Jia Yan,et al.Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films[J].ACTA POLYMERICA SINICA,2021,52(10):1283-1297.
高梦岩,王畅鸥,贾妍等.聚酰亚胺薄膜材料的各向异性导热行为研究与进展[J].高分子学报,2021,52(10):1283-1297. DOI： 10.11777/j.issn1000-3304.2021.21094.

Gao Meng-yan,Wang Chang-ou,Jia Yan,et al.Research Progress in Anisotropic Thermal Conduction Behavior of Polyimide Films[J].ACTA POLYMERICA SINICA,2021,52(10):1283-1297. DOI： 10.11777/j.issn1000-3304.2021.21094.

摘要

聚酰亚胺薄膜材料在集成电路、光电显示、柔性电子等领域具有广泛应用，然而其较差的导热性能越来越无法满足器件的快速散热需求. 在保持耐热、力学等优势性能基础上，发展新一代高导热各向异性的聚酰亚胺薄膜材料成为国内外研究的重点. 本文系统总结了聚酰亚胺本征薄膜及聚酰亚胺/导热填料复合薄膜在各向异性导热行为方面的研究进展，重点从聚酰亚胺分子结构设计、各向异性导热机理、填料取向排列、基体相态结构等方面进行了详细介绍. 通过对非晶型与液晶型两类聚酰亚胺结构特点的分析，阐述了聚酰亚胺本征薄膜的分子结构与各向异性导热性能的关系；介绍了基于导热填料取向排列和基于基体相分离结构两类复合薄膜的填料取向与导热通路构建方法，深入分析了导热填料在基体中的分散形态对薄膜各向异性导热行为的影响，最后对导热聚酰亚胺薄膜材料面临的挑战进行了总结与展望.

Abstract

Polyimide films are widely used in the fields of advanced integrated circuits

optoelectronic displays

flexible functional electronics

etc

. With the further development of application

the poor thermal conductivity of polyimide film is unable to meet the rapid heat dissipation requirements of electronic devices. In order to improve the thermal conductivity of films and maintain the superior performance of polyimide materials

a new generation of anisotropic polyimide films with high thermal conductivity has become the focus of research. Due to the obvious anisotropy in the structure or properties of polyimides and thermally conductive fillers

the thermal conductivity behavior of both polyimide intrinsic films and polyimide-based composite films mostly shows significant anisotropy. The molecular structures and chain aggregation of polyimides

orientation arrangement of thermally conductive fillers

as well as the matrix morphology will all exert an important impact on the thermal conductivity and their anisotropic behavior of films. Here

we systematically summarize the research progress on anisotropic thermal conduction behavior of polyimide intrinsic films and polyimide-based composite films. The molecular structure design of polyimides

anisotropic heat conduction mechanism

filler orientation and matrix phase structures are discussed in detail. The effect of structural characteristics of polyimide intrinsic films on their thermal conductivity in different directions is presented

and the related research results of amorphous polyimides and liquid crystalline polyimides are respectively introduced. Composite films based on the orientation arrangement of thermally conductive fillers are described

and the other polyimide-based composite films with the matrix phase separation structures are also concluded. The relationship between the orientation or dispersed state of thermally conductive fillers in the matrix and the anisotropic thermal conduction behavior of two types composite films are particularly investigated. Finally

the challenges of polyimide-based film materials with high anisotropic thermal conduction are summarized and the prospects of the future work are outlooked.

关键词

聚酰亚胺本征薄膜复合薄膜导热行为各向异性

Keywords

PolyimideIntrinsic filmsComposite filmsThermal conduction behaviorAnisotropy

references

Liaw D J, Wang K L, Huang Y C, Lee K R, Lai J Y, Ha C S. Prog Polym Sci, 2012, 37(7): 907-974. doi:10.1016/j.progpolymsci.2012.02.005http://dx.doi.org/10.1016/j.progpolymsci.2012.02.005

Zhai L, Yang S Y, Fan L. Polymer, 2012, 53(16): 3529-3539. doi:10.1016/j.polymer.2012.05.047http://dx.doi.org/10.1016/j.polymer.2012.05.047

Ma P C, Dai C T, Wang H Z, Li Z K, Liu H B, Li W M, Yang C L. Compos Commun, 2019, 16: 84-93. doi:10.1016/j.coco.2019.08.011http://dx.doi.org/10.1016/j.coco.2019.08.011

Bai L, Zhai L, He M H, Wang C O, Mo S, Fan L. React Funct Polym, 2019, 141: 155-164. doi:10.1016/j.reactfunctpolym.2019.05.009http://dx.doi.org/10.1016/j.reactfunctpolym.2019.05.009

Luo Longbo(罗龙波), Ye Xinhe(叶信合), Yi Jiang(易江), Li Ke(李科), Liu Xiangyang(刘向阳). Acta Polymerica Sinica(高分子学报), 2021, 52(4): 363-370

Bai Lan(白兰), Zhai Lei(翟磊), He Minhui(何民辉), Wang Changou(王畅鸥), Mo Song(莫松), Fan Lin(范琳).Acta Polymerica Sinica(高分子学报), 2019, 50(12): 1305-1313

Yin Chuangen(尹传根), Fan Jinchen(范金辰), Min Yulin(闵宇霖), Xu Qunjie(徐群杰). Insulating Materials(绝缘材料), 2017, 50(8): 34-40

Wei Shiyang(魏世洋), Zheng Zhibo(郑智博), Yu Qiaoxi(余桥溪), Fan Zhenguo(范振国), Liu Siwei(刘四委), Chi Zhenguo(池振国), Zhang Yi(张艺), Xu Jiarui(许家瑞). Acta Polymerica Sinica(高分子学报), 2019, 50(4): 1-8

Chen H Y, Ginzburg V V, Yang J, Yang Y F, Liu W, Huang Y, Du L B, Chen B. Prog Polym Sci, 2016, 59: 41-85. doi:10.1016/j.progpolymsci.2016.03.001http://dx.doi.org/10.1016/j.progpolymsci.2016.03.001

Burger N, Laachachi A, Ferriol M, Lutz M, Toniazzo V, Ruch D. Prog Polym Sci, 2016, 61: 1-28. doi:10.1016/j.progpolymsci.2016.05.001http://dx.doi.org/10.1016/j.progpolymsci.2016.05.001

Yang Xuewei(杨雪薇), Li Rui(李睿), Zhao Ning(赵宁), Xu Jian(徐坚). Polymer Bulletin(高分子通报), 2020, (12): 1-8

Gu J W, Lv Z Y, Wu Y L, Guo Y Q, Tian L D, Qiu H, Li W Z, Zhang Q Y. Compos Part A-Appl S, 2017, 94: 209-216. doi:10.1016/j.compositesa.2016.12.014http://dx.doi.org/10.1016/j.compositesa.2016.12.014

Liu D X, Ma C G, Chi H T, Li S H, Zhang P, Dai P B. RSC Adv, 2020, 10(69): 42584-42595. doi:10.1039/d0ra08048ahttp://dx.doi.org/10.1039/d0ra08048a

Wang Haitao(王海涛), Ding Dongliang(丁栋梁), Liu Qian(刘乾), Chen Yanhui(陈妍慧), Zhang Qiuyu(张秋禹). Polymer Materials Science and Engineering(高分子材料科学与工程), 2019, 35(8): 159-166

Ding D L, Wang H T, Wu Z Q, Chen Y H, Zhang Q Y. Macromol Rapid Commun, 2019: 1800805. doi:10.1002/marc.201800805http://dx.doi.org/10.1002/marc.201800805

Huang X Y, Jiang P K, Toshikatsu T. IEEE Electr Insul M, 2011, 27: 8-16

Wu Y M, Ye K, Liu Z D, Wang M J, Chee K W A, Lin C T, Jiang N, Yu J H. J Mater Chem C, 2018, 6: 6494-6501. doi:10.1039/c8tc01464ghttp://dx.doi.org/10.1039/c8tc01464g

Han J K, Du G L, Gao W W, Bai H. Adv Funct Mater, 2019, 29: 1900412. doi:10.1002/adfm.201900412http://dx.doi.org/10.1002/adfm.201900412

Lei C X, Wu K, Wu L Y, Liu W J, Du R N, Chen F, Fu Q. J Mater Chem C, 2019, 7: 19364-19373. doi:10.1039/c9ta05067ahttp://dx.doi.org/10.1039/c9ta05067a

Zhang P, Zhang X, Ding X, Wang Y Y, Shu M T, Zeng X L, Gong Y, Zheng K, Tian X Y. Nanotechnology, 2020, 31(47): 475709. doi:10.1088/1361-6528/abaf82http://dx.doi.org/10.1088/1361-6528/abaf82

Zhang M, Liu W L, Gao X, Cui P, Zou T, Hu G H, Tao L M, Zhai L. Polymers, 2020, 12: 1532. doi:10.3390/polym12071532http://dx.doi.org/10.3390/polym12071532

Huag C, Li J H, Sun D L, Xuan R, Sui Y Y, Li T Y, Shang L, Zhang G P, Sun R, Wong C P. J Mater Chem C, 2020, 8: 14886-14894

Kurabayashi K, Goodson K E. J Appl Phys, 1999, 86(4): 1925-1931. doi:10.1063/1.370989http://dx.doi.org/10.1063/1.370989

Kurabayashi K, Asheghi M, Touzelbaev M, Goodson K E. J Microelectromech Syst, 1999, 8(2): 180-191. doi:10.1109/84.767114http://dx.doi.org/10.1109/84.767114

Morikawa J, Hashimoto T. J Appl Phys, 2009, 105(11): 113506. doi:10.1063/1.3116509http://dx.doi.org/10.1063/1.3116509

Yorifuji D, Ando S. Macromolecules, 2010, 43(18): 7583-7593. doi:10.1021/ma101066phttp://dx.doi.org/10.1021/ma101066p

Wang M, Wang J, Yang H, Lin B P, Chen E Q, Keller P, Zhang X Q, Sun Y. Chem Commun, 2016, 52(23): 4313-4316. doi:10.1039/c6cc00081ahttp://dx.doi.org/10.1039/c6cc00081a

Ge S J, Zhao T P, Wang M, Deng L L, Lin B P, Zhang X Q, Sun Y, Yang H, Chen E Q. Soft Matter, 2017, 13(32): 5463-5468. doi:10.1039/c7sm01154ghttp://dx.doi.org/10.1039/c7sm01154g

Tatsuo I K, Ken I, Junji W. Macromolecules, 1997, 30: 4244-4246. doi:10.1021/ma9704370http://dx.doi.org/10.1021/ma9704370

Tatsuo I, Masa-aki K, Yoshio I, Junji W. Macromol Chem Phys, 1997, 198: 519-530. doi:10.1002/macp.1997.021980224http://dx.doi.org/10.1002/macp.1997.021980224

Hsu W H, Tatsuo I K, Kazuyuki H, Junji W. Polymer, 1999, 40: 3821-3828. doi:10.1016/s0032-3861(98)00589-8http://dx.doi.org/10.1016/s0032-3861(98)00589-8

Costa G, Eastmond G C, Fairclough J P A, Paprotny J, Ryan A J, Stagnaro P. Macromolecules, 2008, 41: 1034-1040. doi:10.1021/ma071665phttp://dx.doi.org/10.1021/ma071665p

Shoji Y, Higashihara T, Watanabe J, Ueda M. Chem Lett, 2009, 38(7): 716-717. doi:10.1246/cl.2009.716http://dx.doi.org/10.1246/cl.2009.716

Theo J D, Eduardo M, Jeffrey J H, Erik S W, Terry L S. Macromolecules, 2008, 41: 2474-2483

Shoji Y, Ishige R, Higashihara T, Watanabe J, Ueda M. Macromolecules, 2010, 43(2): 805-810. doi:10.1021/ma9021828http://dx.doi.org/10.1021/ma9021828

Shoji Y, Ishige R, Higashihara T, Kawauchi S, Watanabe J, Ueda M. Macromolecules, 2010, 43(21): 8950-8956. doi:10.1021/ma101751ehttp://dx.doi.org/10.1021/ma101751e

Shoji Y, Ishige R, Higashihara T, Morikawa J, Hashimoto T, Takahara A, Watanabe J, Ueda M. Macromolecules, 2013, 46(3): 747-755. doi:10.1021/ma302486shttp://dx.doi.org/10.1021/ma302486s

Sasaki R, Takahashi Y, Hayashi Y, Kawauchi S. J Phys Chem B, 2020, 124(5): 881-889. doi:10.1021/acs.jpcb.9b08158http://dx.doi.org/10.1021/acs.jpcb.9b08158

Guerra V, Wan C Y, McNally T. Prog Mater Sci, 2019, 100: 170-186. doi:10.1016/j.pmatsci.2018.10.002http://dx.doi.org/10.1016/j.pmatsci.2018.10.002

Ruan K P, Shi X T, Guo Y Q, Gu J W. Compos Commun, 2020, 22: 100518. doi:10.1016/j.coco.2020.100518http://dx.doi.org/10.1016/j.coco.2020.100518

Meziani M J, Song W L, Wang P, Lu F S, Hou Z L, Anderson A, Maimaiti H, Sun Y P. Chemphyschem, 2015, 16: 1339-1346. doi:10.1002/cphc.201402814http://dx.doi.org/10.1002/cphc.201402814

Yang N N, Zeng X L, Lu J B, Sun R, Wong C P. Appl Phys Lett, 2018, 113: 171904. doi:10.1063/1.5050293http://dx.doi.org/10.1063/1.5050293

Zhou S S, Xu T L, Jiang F, Song N, Shi L Y, Ding P. J Mater Chem C, 2019, 7: 13896-13903. doi:10.1039/c9tc04381khttp://dx.doi.org/10.1039/c9tc04381k

Chen J, Huang X Y, Sun B, Jiang P K. ACS Nano, 2019, 13(1): 337-345. doi:10.1021/acsnano.8b06290http://dx.doi.org/10.1021/acsnano.8b06290

Dong J, Cao L, Li Y, Wu Z Q, Teng C Q. Compos Sci Technol, 2020, 196: 108242. doi:10.1016/j.compscitech.2020.108242http://dx.doi.org/10.1016/j.compscitech.2020.108242

Cao L, Wang J J, Dong J, Zhao X, Li H B, Zhang Q H. Compos Part B-Eng, 2020, 188: 107882. doi:10.1016/j.compositesb.2020.107882http://dx.doi.org/10.1016/j.compositesb.2020.107882

Ma L L, Wang B X, Zhao S Y, Hao C C, Guo H Q, Lei Q Q. J Mater Sci Mater Electron, 2019, 30: 20302-20310. doi:10.1007/s10854-019-02417-3http://dx.doi.org/10.1007/s10854-019-02417-3

Li L H, Chen Y, Behan G, Zhang H Z, Petravic M, Glushenkov A M. J Mater Chem, 2011, 21(32): 11862-11866. doi:10.1039/c1jm11192bhttp://dx.doi.org/10.1039/c1jm11192b

Xiao F, Naficy S, Casillas G, Khan M H, Katkus T, Jiang L, Liu H K, Li H J, Huang Z G. Adv Mater, 2015, 27(44): 7196-7203. doi:10.1002/adma.201502803http://dx.doi.org/10.1002/adma.201502803

Wang M J, Jiao Z Y, Chen Y P, Hou X, Fu L, Wu Y M, Li S Y, Jiang N, Yu J H. Compos Part A-Appl S, 2018, 109: 321-329. doi:10.1016/j.compositesa.2018.03.023http://dx.doi.org/10.1016/j.compositesa.2018.03.023

Min Y J, Kang K H, Kim D E. Nano Res, 2018, 11(5): 2366-2378. doi:10.1007/s12274-017-1856-0http://dx.doi.org/10.1007/s12274-017-1856-0

Wang T, Wang M J, Fu L, Duan Z H, Chen Y P, Hou X, Wu Y M, Li S Y, Guo L C, Kang R Y, Jiang N, Yu J H. Sci Rep, 2018, 8(1): 1557. doi:10.1038/s41598-018-19945-3http://dx.doi.org/10.1038/s41598-018-19945-3

Hwang G H, Kwon Y S, Lee J S, Jeong Y G. J Appl Polym Sci, 2020: 50324. doi:10.1002/app.50324http://dx.doi.org/10.1002/app.50324

Tanimoto M, Yamagata T, Miyata K, Ando S. ACS Appl Mater Interfaces, 2013, 5(10): 4374-4382. doi:10.1021/am400615zhttp://dx.doi.org/10.1021/am400615z

Tanimoto M, Ando S. Compos Sci Technol, 2016, 123: 268-275. doi:10.1016/j.compscitech.2015.12.022http://dx.doi.org/10.1016/j.compscitech.2015.12.022

Haruki M, Tada J, Funaki R, Onishi H, Tada Y. Thermochim Acta, 2020, 684: 178491. doi:10.1016/j.tca.2019.178491http://dx.doi.org/10.1016/j.tca.2019.178491

Wu S Y, Ladani R B, Zhang J, Bafekrpour E, Ghorbani K, Mouritz A P, Kinloch A J, Wang C H. Carbon, 2015, 94: 607-618. doi:10.1016/j.carbon.2015.07.026http://dx.doi.org/10.1016/j.carbon.2015.07.026

Kim K, Ju H, Kim J. Compos Sci Technol, 2016, 123: 99-105. doi:10.1016/j.compscitech.2015.12.004http://dx.doi.org/10.1016/j.compscitech.2015.12.004

Lin Z Y, Liu Y, Raghavan S, Moon K S, Sitaraman S K, Wong C P. ACS Appl Mater Interfaces, 2013, 5(15): 7633-7640. doi:10.1021/am401939zhttp://dx.doi.org/10.1021/am401939z

Yorifuji D, Ando S. J Mater Chem, 2011, 21(12): 4402-4407. doi:10.1039/c0jm04243ahttp://dx.doi.org/10.1039/c0jm04243a

Yuan D B, Gao Y F, Guo Z X, Yu J. J Appl Polym Sci, 2017, 134(40): 45371. doi:10.1002/app.45371http://dx.doi.org/10.1002/app.45371

Yorifuji D, Ando S. Macromol Chem Phys, 2010, 211(19): 2118-2124. doi:10.1002/macp.201000294http://dx.doi.org/10.1002/macp.201000294

Chae B, Hong D G, Jung Y M, Won J C, Lee S W. Spectrochim Acta A, 2018, 195: 1-6. doi:10.1016/j.saa.2018.01.025http://dx.doi.org/10.1016/j.saa.2018.01.025

Uchida S, Murakami T, Iwamura T, Ishige R, Ando S. RSC Advances, 2017, 7(25): 15492-15499. doi:10.1039/c7ra00760dhttp://dx.doi.org/10.1039/c7ra00760d

Uchida S, Ishige R, Ando S. Polymers, 2017, 9(7): 263. doi:10.3390/polym9070263http://dx.doi.org/10.3390/polym9070263

Zhang G D, Fan L, Bai L, He M H, Zhai L, Mo S. Chinese J Polym Sci, 2018, 36(12): 1394-1402. doi:10.1007/s10118-018-2155-2http://dx.doi.org/10.1007/s10118-018-2155-2

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