Thermogravimetric Analysis and Its Applications in Polymer Characterization

Qi-yuan Xie; Dan-dan Chen; Yan-wei Ding

doi:10.11777/j.issn1000-3304.2021.21210

您当前的位置：

首页 >

文章列表页 >

Thermogravimetric Analysis and Its Applications in Polymer Characterization

Review (Special Topic: Techniques of Polymer Characterization) | 更新时间：2024-10-08

- Thermogravimetric Analysis and Its Applications in Polymer Characterization
- ACTA POLYMERICA SINICA Vol. 53, Issue 2, Pages: 193-210(2022)
- 作者机构：
  
  1.中国科学技术大学，火灾科学国家重点实验室，合肥 230026
  2.中国科学技术大学，合肥微尺度物质科学国家研究中心，合肥 230026
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21210
  CLC：
- Published：20 February 2022，
  
  Published Online：22 December 2021，
  
  Received：03 August 2021，
  
  Revised：18 October 2021，
- 稿件说明：
移动端阅览
谢启源,陈丹丹,丁延伟.热重分析技术及其在高分子表征中的应用[J].高分子学报,2022,53(02):193-210.

Xie Qi-yuan,Chen Dan-dan,Ding Yan-wei.Thermogravimetric Analysis and Its Applications in Polymer Characterization[J].ACTA POLYMERICA SINICA,2022,53(02):193-210.
谢启源,陈丹丹,丁延伟.热重分析技术及其在高分子表征中的应用[J].高分子学报,2022,53(02):193-210. DOI： 10.11777/j.issn1000-3304.2021.21210.

Xie Qi-yuan,Chen Dan-dan,Ding Yan-wei.Thermogravimetric Analysis and Its Applications in Polymer Characterization[J].ACTA POLYMERICA SINICA,2022,53(02):193-210. DOI： 10.11777/j.issn1000-3304.2021.21210.

摘要

热重分析技术(TGA)是在程序控制温度和设定气氛下表征材料受热过程中的质量随温度或时间变化的高精度研究工具，具有重复性好、灵敏度高和热过程控制精准等优点. 近年来，TGA技术在高分子材料领域得到了广泛应用，促进了高分子材料热稳定性、组成分析以及热分解机理等材料细观热响应特性的深入研究. 本文分别从热重分析基本原理、仪器校准、实验方案设计、实验操作、热重曲线综合解析以及各环节中易出现的不当操作、异常数据与解决方案等方面进行阐述，并给出了在高分子科学研究领域中的典型应用案例、未来发展趋势及机遇与挑战. 在实际应用中，基于TGA与傅里叶红外光谱(FTIR)、示差扫描量热法(DSC)、气相色谱-质谱联用(GC/MS)等技术的联用分析，将有利于进一步揭示高分子材料在不同气氛和热激励等条件下的详细热响应信息，为性能优异的新型高分子材料研发与设计、热解机理及燃烧蔓延动力学等领域提供支撑和指导.

Abstract

Thermogravimetric analysis (TGA) is an efficient research tool that characterizes the weight of materials with temperature or time under a program controlled temperature and a certain atmosphere. One of its advantages is that the TGA results can be well repeated with high sensitivity. In addition

its heating process is accurately and flexibly controlled according to real thermal environment of samples. In recent years

TGA is popularly used in the field of polymer materials

which promotes the detailed analyses on their thermal stability

composition analysis and thermal decomposition mechanism

et al

. This review covers many aspects of TGA

including basic principles

calibration

scheme design

curve analysis

as well as those common errors during sample preparation and experiments

abnormal data figuring and the solution to them. Additionally

the typical application cases of TGA in polymer science

as well as their opportunity and challenges in future

are also presented. In the applications of TGA technology

more information about the thermal-response behavior of polymers under different atmosphere and heating conditions could be revealed by TGA coupled with FTIR

DSC

GC/MS technologies. In this case

not only the weight information of sample during a specific heating condition

but also the endothermic and exothermic behaviors

released gas components at the same time can be analyzed together. They are helpful for new polymer design

thermal decomposition mechanism and flame sprea

d models development.

关键词

热重分析技术曲线解析热稳定性热解机理案例分析

Keywords

Thermogravimetric analysisCurve analysisThermal stabilityThermal decomposition mechanismCase analysis

references

Seifia H, Gholamib T, Seific S, Ghoreishia S M, Salavati-Niasarib M. J Anal Appl Pyrolysis, 2020, 149: 104840. doi:10.1016/j.jaap.2020.104840http://dx.doi.org/10.1016/j.jaap.2020.104840

Peñalver R, Arroyo-Manzanares N, Lopez-García I, Hernández-Córdoba M. Chemosphere， 2020, 242: 125170. doi:10.1016/j.chemosphere.2019.125170http://dx.doi.org/10.1016/j.chemosphere.2019.125170

Chen Yongxuan(陈咏萱), Zhou Dongshan(周东山), Hu Wenbing(胡文兵). Acta Polymerica Sinica(高分子学报), 2021, 52(4): 423-444. doi:10.11777/j.issn1000-3304.2020.20234http://dx.doi.org/10.11777/j.issn1000-3304.2020.20234

Ding Yanwei(丁延伟). Fundamentals of Thermal Analysis(热分析基础). Hefei(合肥): University of Science and Technology of China Press(中国科学技术大学出版社), 2020. doi:10.3866/pku.dxhx202012012http://dx.doi.org/10.3866/pku.dxhx202012012

GB/T 6425-2008 Nomenclature for Thermal Analysis(热分析术语). National Standards of People’s Republic of China(中华人民共和国国家标准), 2008. doi:10.1016/S1734-1140(13)71006-5http://dx.doi.org/10.1016/S1734-1140(13)71006-5

I Haines P J, Thermal Methods of Analysis: Principles, Applications and Problems. Springer Science+Business Media: Dordrecht， 1995. Chap1. doi:10.1007/bf02548698http://dx.doi.org/10.1007/bf02548698

Norem S D, O’Neill M J, Gray A P. Thermochim Acta, 1970, 1: 29-38. doi:10.1016/0040-6031(70)85026-2http://dx.doi.org/10.1016/0040-6031(70)85026-2

Gallagher P K, Schrey F. Thermochim Acta, 1970, 1: 465-476. doi:10.1016/0040-6031(70)85017-1http://dx.doi.org/10.1016/0040-6031(70)85017-1

Ozkan U S, Kumthekar M K, Karakas G. J Catal, 1997, 171: 67-76. doi:10.1006/jcat.1997.1793http://dx.doi.org/10.1006/jcat.1997.1793

McGhie A R. Anal Chem, 1983, 55: 987-988. doi:10.1021/ac00257a047http://dx.doi.org/10.1021/ac00257a047

McGhie A R, Chiu J, Fair P G, Blaine R L. Thermochim Acta, 1983, 67: 241-250. doi:10.1016/0040-6031(83)80104-xhttp://dx.doi.org/10.1016/0040-6031(83)80104-x

Brown M E, Bhengu T T, Sanyal D K. Thermochim Acta, 1994, 242: 141-152. doi:10.1016/0040-6031(94)85016-xhttp://dx.doi.org/10.1016/0040-6031(94)85016-x

Gallagher P K, Zhong Z, Charsley E L, Mikhail S A, Todoki M, Tanaguchi K, Blaine R L. J Therm Anal, 1993, 40: 1423-1430. doi:10.1007/bf02546906http://dx.doi.org/10.1007/bf02546906

Weddle B J, Robbins S A, Gallagher P K. Pure Appl Chem, 1995, 67: 1843-1847. doi:10.1351/pac199567111843http://dx.doi.org/10.1351/pac199567111843

Gundlach E M, Gallagher P K. J Therm Anal, 1997, 49: 1013-1016. doi:10.1007/bf01996788http://dx.doi.org/10.1007/bf01996788

JJG 014-1996 Verification Regulation for Thermal Analyzer(热分析仪检定规程). National Education Commission of People’s Republic of China(中华人民共和国国家教育委员会), 1996. doi:10.1007/978-1-349-24516-1_6http://dx.doi.org/10.1007/978-1-349-24516-1_6

JJG 1135-2017 Verification Regulation for Thermogravimetric Analyzer(热重分析仪检定规程). General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, 2017. doi:10.2753/clg0009-4609390303http://dx.doi.org/10.2753/clg0009-4609390303

JJG 936-2002 Verification Regulation for Differential Scanning Calorimeter(示差扫描热量计检定规程). General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, 2002. doi:10.1007/BF02856701http://dx.doi.org/10.1007/BF02856701

Ding Yanwei(丁延伟), Zheng Kang(郑康), Qian Yixiang(钱义祥). Introduction to Thermal Analysis Experiment Design and Curve Analysis(热分析实验方案设计与曲线解析概论). Beijing(北京): Chemical Industry Press(化学工业出版社), 2020

Gibert JP, Lopez Cuesta JM, Bergeret A, Crespy A. Polym Degrad Stab, 2000, 67: 437-447. doi:10.1016/s0141-3910(99)00142-1http://dx.doi.org/10.1016/s0141-3910(99)00142-1

Schindler A, Doedt M, Gezgin S, Menzel J, Schmolzer S. J Therm Anal Calorim, 2017, 129: 833-842. doi:10.1007/s10973-017-6208-5http://dx.doi.org/10.1007/s10973-017-6208-5

Vogel C, Kruger O, Adam C. J Therm Anal Calorim, 2016, 123: 1045-1051. doi:10.1007/s10973-015-5016-zhttp://dx.doi.org/10.1007/s10973-015-5016-z

Yuan Y, Ma C, Shi Y Q, Song L, Hu Y, Hu W Z. Mater Chem Phys, 2018, 211: 42-53. doi:10.1016/j.matchemphys.2018.02.007http://dx.doi.org/10.1016/j.matchemphys.2018.02.007

Wang Fang(王芳), Hao Jianwei(郝建薇), Li Zhuoshi(李茁实), Zou Hongfei(邹红飞). Acta Polymerica Sinica(高分子学报), 2016, (7): 860-870. doi:10.11777/j.issn1000-3304.2016.15329http://dx.doi.org/10.11777/j.issn1000-3304.2016.15329

Dorez G, Taguet A, Ferry L, Lopez Cuesta J M. Polym Degrad Stab, 2014, 102: 152-159. doi:10.1016/j.polymdegradstab.2014.01.018http://dx.doi.org/10.1016/j.polymdegradstab.2014.01.018

Hatakeyama H, J Therm Anal Calorim, 2014, 118: 23-30. doi:10.1007/s10973-014-3959-0http://dx.doi.org/10.1007/s10973-014-3959-0

Gerassimidou S, Velis C A, Williams P T, Komilis D. Waste Manage Res, 2020, 38(9): 942-965. doi:10.1177/0734242x20941085http://dx.doi.org/10.1177/0734242x20941085

Rego F, Dias A P S, Gasguilho M, Rosa F C, Rodrigues A. Biomass Bioenerg, 2019, 122: 375-380. doi:10.1016/j.biombioe.2019.01.037http://dx.doi.org/10.1016/j.biombioe.2019.01.037

Zhang W J, Shi X H, Zhang Y X, Gu W, Li B Y, Xian Y Z. J Mater Chem A, 2013, 1: 1745-1753. doi:10.1039/c2ta00294ahttp://dx.doi.org/10.1039/c2ta00294a

Passauer L. Prog Org Coat, 2021, 157: 106331. doi:10.1016/j.porgcoat.2021.106331http://dx.doi.org/10.1016/j.porgcoat.2021.106331

Mas I, Hortelano, Ruiz-Bermejo M, Fuente J L. Eur Polym J, 2021, 143: 110185. doi:10.1016/j.eurpolymj.2020.110185http://dx.doi.org/10.1016/j.eurpolymj.2020.110185

Laidler K J. J Chem Educ, 1984, 61(6): 494-498. doi:10.1021/ed061p494http://dx.doi.org/10.1021/ed061p494

Harcourt A V. Phil Trans R. Soc Lond A, 1913, 212: 187-204

Freeman E S. Carroll B. J Phys Chem, 1958, 62(4): 394-397. doi:10.1021/j150562a003http://dx.doi.org/10.1021/j150562a003

Newkirk A E. Anal Chem, 1960, 32(12): 1558-1563. doi:10.1021/ac60168a006http://dx.doi.org/10.1021/ac60168a006

Sharp J H, Wentworth S A. Anal Chem, 1969, 41(14): 2060-2062. doi:10.1021/ac50159a046http://dx.doi.org/10.1021/ac50159a046

Kissinger H E. Anal Chem, 1957, 29(11): 1702-1706. doi:10.1021/ac60131a045http://dx.doi.org/10.1021/ac60131a045

Friedman H L. J Polym Sci, Part C: Polym Symp, 1964, 6: 183-195. doi:10.1002/polc.5070060121http://dx.doi.org/10.1002/polc.5070060121

Vachuska J, Voboril M. Thermochim Acta, 1971, 2(5): 379-392. doi:10.1016/0040-6031(71)85014-1http://dx.doi.org/10.1016/0040-6031(71)85014-1

Horowitz H H, Metzger G. Analy Chem, 1963, 35(10): 1464-1468. doi:10.1021/ac60203a013http://dx.doi.org/10.1021/ac60203a013

Dharwadkar S, Karkhanavala M. Therm Anal, 1980, 18(1): 185-191. doi:10.1007/bf01909466http://dx.doi.org/10.1007/bf01909466

Coats A W, Redfern J. Nature, 1964, 201(4914): 68-69. doi:10.1038/201068a0http://dx.doi.org/10.1038/201068a0

Ozawa T. Bull Chem Soc Jpn, 1965, 38(11): 1881-1886. doi:10.1246/bcsj.38.1881http://dx.doi.org/10.1246/bcsj.38.1881

Flynn J H, Wall L A. J Res Nat Bur Stand, 1966, 70(6): 487-523. doi:10.6028/jres.070a.043http://dx.doi.org/10.6028/jres.070a.043

Flynn J H, Wall L A. J Polym Sci, Part B: Polym Lett, 1966, 4(5): 323-328. doi:10.1002/pol.1966.110040504http://dx.doi.org/10.1002/pol.1966.110040504

Zsako J. J Phys Chem, 1968, 72(7): 2406-2411. doi:10.1021/j100853a022http://dx.doi.org/10.1021/j100853a022

Satava V. Thermochim Acta, 1971, 2(5): 423-428. doi:10.1016/0040-6031(71)85018-9http://dx.doi.org/10.1016/0040-6031(71)85018-9

Tang X Y, Xie Q Y, Qiu R, Yang Y. Polym Degrad Stab, 2018, 154: 10-26. doi:10.1016/j.polymdegradstab.2018.05.016http://dx.doi.org/10.1016/j.polymdegradstab.2018.05.016

Views

756

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Effect of Amylose Derivatives on Thermal Properties of Poly(methyl methacrylate)

Study on the Abnormal High Temperature Thermal Stability of Polymer:Fullerene Photovoltaic Cells

Fabrication of a La-based Metal Organic Framework and Its Effect on Fire Safety and Thermal Stability of Polycarbonate

Synergistic Flame Retardancy of Amine-based Multi-walled Carbon Nanotubes/DOPO Derivatives and Its Effect on the Properties of Nylon 6

Related Author

Wei Zhao

Xiao Dai

Li-li Zhang

Jun Shen

Wen-sheng Zhao

Yong-zhen Yang

Hua Wang

Xu-guang Liu

Related Institution

School of Civil and Resource Engineering, University of Science and Technology Beijing

College of Materials Science and Chemical Engineering, Harbin Engineering University

Printed Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences (CAS)

College of Textile Engineering, Taiyuan University of Technology

Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰