Carbonized Polymer Dots: a Novel Single-particle Organic-inorganic Hybrid System

Yi Ru; Si-yu Lu

doi:10.11777/j.issn1000-3304.2022.22065

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Carbonized Polymer Dots: a Novel Single-particle Organic-inorganic Hybrid System

Feature Article | 更新时间：2024-10-08

- Carbonized Polymer Dots: a Novel Single-particle Organic-inorganic Hybrid System
- ACTA POLYMERICA SINICA Vol. 53, Issue 7, Pages: 812-827(2022)
- 作者机构：
  
  郑州大学化学学院绿色催化中心郑州 450000
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22065
  CLC：
- Published：20 July 2022，
  
  Published Online：23 May 2022，
  
  Accepted：06 April 2022
- 稿件说明：
移动端阅览
茹艺,卢思宇.碳化聚合物点：一种新型的单颗粒有机无机杂化体系[J].高分子学报,2022,53(07):812-827.

Ru Yi,Lu Si-yu.Carbonized Polymer Dots: a Novel Single-particle Organic-inorganic Hybrid System[J].ACTA POLYMERICA SINICA,2022,53(07):812-827.
茹艺,卢思宇.碳化聚合物点：一种新型的单颗粒有机无机杂化体系[J].高分子学报,2022,53(07):812-827. DOI： 10.11777/j.issn1000-3304.2022.22065.

Ru Yi,Lu Si-yu.Carbonized Polymer Dots: a Novel Single-particle Organic-inorganic Hybrid System[J].ACTA POLYMERICA SINICA,2022,53(07):812-827. DOI： 10.11777/j.issn1000-3304.2022.22065.

摘要

碳化聚合物点(CPDs)指通过自下而上法，经聚合、交联、碳化而形成的一种具有特殊的碳核和聚合物壳杂化结构. 这种特殊的杂化结构赋予了CPDs独特的光学、电学等物理化学性质，作为一种新兴的零维碳纳米材料受到了广泛的研究关注. 本文通过系统地总结与分析，强调了CPDs聚合-碳化的本质，把CPDs看作是一种新型的单颗粒有机无机杂化体系，并从CPDs的结构特点、制备、光电性质及其在光学和催化领域的应用4个角度总结了CPDs的研究进展. 重点介绍了郑州大学碳点研究中心在CPDs的可控制备、发光机理、光学和催化领域的应用相关的研究工作，论述了CPDs未来发展所面临的问题与方向.

Abstract

Carbonized polymer dots (CPDs) is a kind of carbon-based nanomaterial with a new hybrid structure of carbon core and polymer shell

which is formed by polymerization

crosslinking and carbonization of small molecules

polymers or biomass through bottom-up methods. This special hybrid structure endows CPDs with many unique optical

electrical and other physical and chemical properties. For example

hig

h fluorescence quantum yield

easy surface functionalization

high chemical stability

photobleaching resistance

low toxicity

etc

make CPDs show great application potential in biomedicine

catalysis

photoelectric devices

sensing

anti-counterfeiting and other fields. As an emerging kind of zero-dimensional carbon nanomaterials

CPDs has received extensive research attentions. Here

through the summary and analysis of the relevant literature

we emphasize the importance of polymerization and carbonization on the structure and properties of CPDs

and it is seen as a new type of single-particle organic inorganic hybrid system. We summarize the research progress of CPDs from four perspectives: the structural characteristics

preparation

photoelectric properties and their applications in the fields of optics and catalysis. The emphasis of this review is especially focused on our research work on the fields of controllable preparation

luminescence mechanism

optical and catalytic applications

and discusses the problems and important development direction of CPDs in the future.

关键词

碳化聚合物点核壳结构有机无机杂化可控制备光电性质

Keywords

Carbonized polymer dotsCore-shell structureInorganic-organic hybridControllable preparationPhotoelectric properties

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