Recent Advances in Solid-State Polymer Electrolytes

Chuan Luo; Li-hua Hu; Chun-peng Ning; Kan Yue; Zi-hao Guo

doi:10.11777/j.issn1000-3304.2025.25106

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Recent Advances in Solid-State Polymer Electrolytes

更新时间：2025-07-28

- Recent Advances in Solid-State Polymer Electrolytes
- Acta Polymerica Sinica Pages: 1-21(2025)
- 作者机构：
  
  华南理工大学前沿软物质学院发光材料与器件全国重点实验室广东省功能与智能杂化材料与器件重点实验室广州 510640
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25106
  CLC：
- CSTR：32057.14.GFZXB.2025.7436
- Received：20 April 2025，
  
  Accepted：03 June 2025，
  
  Published Online：28 July 2025，
- 稿件说明：
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罗川, 胡利华, 宁春棚, 岳衎, 郭子豪. 固态聚合物电解质的最新研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25106

Luo, C.; Hu, L. H.; Ning, C. P.; Yue, K.; Guo, Z. H. Recent advances in solid-state polymer electrolytes. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25106
罗川, 胡利华, 宁春棚, 岳衎, 郭子豪. 固态聚合物电解质的最新研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25106 DOI： CSTR： 32057.14.GFZXB.2025.7436.

Luo, C.; Hu, L. H.; Ning, C. P.; Yue, K.; Guo, Z. H. Recent advances in solid-state polymer electrolytes. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2025.25106 DOI： CSTR： 32057.14.GFZXB.2025.7436.

摘要

具备高能量密度和安全性的全固态电池技术已成为下一代先进储能体系的核心发展方向. 固态聚合物电解质(SPE)因其轻质化特征、成本效益优势、优异加工性能及本质阻燃特性，展现出替代传统液态电解质实现规模化商业应用的潜力. 然而，传统商业化SPE受限于其固有电化学性能缺陷，已难以适配当前高能量密度电池体系对电解质材料的严苛性能要求. 尽管通过杂化改性、共混优化、掺杂调控等物理工艺制备的凝胶电解质及无机复合电解质可部分满足现有锂金属电池(LMB)的应用需求，但开发兼具本征高离子电导率与宽电化学窗口的SPE仍是当前储能材料领域的关键科学命题. 本篇综述简要概述了全固态聚合物电解质领域的最新研究进展，并系统地整理与分类了新型SPE的主流设计策略. 这些策略涵盖多维拓扑结构的设计、阴离子锚定策略、聚合物氟化工程、弱溶剂化主链构筑以及其他创新性设计理念. 各章节分别介绍了基于上述策略研发的新型SPE，并展示了其在LMB里的实际应用表现. 最后，本文为如何设计更安全、电化学性能更优异的SPE提供了个人见解与展望.

Abstract

Solid-state battery with high energy density and safety has become the popular development direction for the next-generation advanced energy storage systems. Solid-state polymer electrolytes (SPEs) have demonstrated the potential with which to replace traditional liquid electrolytes for large-scale commercial applications due to their lightweight features

cost-effectiveness

excellent processability

and intrinsic flame-retardant properties. However

traditional commercial SPEs are limited by their intrinsic electrochemical shortcomings

which make it difficult to meet the stringent performance requirements for electrolyte in current high-energy-density battery. Although gel-type electrolytes and inorganic composite electrolytes prepared by physical processes such as hybridization modification

blend optimization

and doping modulation can partially meet the application requirements of lithium metal batteries (LMBs)

the development of SPEs with intrinsically high ionic conductivity and wide electrochemical windows is still a key scientific proposition in the field of energy storage materials. This feature article provides a brief overview of recent advances in the field of all-solid-state polymer electrolytes as well as systematically summarizes the main design strategies for novel SPEs. These strategies include the design of multidimensional topologies

anion-anchoring strategies

polymer fluorination engineering

weakly-solvating mainchain construction

and other innovative design concepts. Each part presents the novel SPEs developed based on the above strategies and demonstrates their practical application in LMBs. Finally

this article provides insights into the design of safer SPEs with superior electrochemical performance.

关键词

Keywords

references

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Qingdao Industrial Energy Storage Technology Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences

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