Advances in Chlorinated Poly(vinyl chloride): from Modification to Functional Applications

Long Zhang; Qi-ning Ke; Le-wen Liu; Yan-an Chen; Sheng-wen Zou; Peng Qin; Shao-yun Guo

doi:10.11777/j.issn1000-3304.2025.25109

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Advances in Chlorinated Poly(vinyl chloride): from Modification to Functional Applications

Review | 更新时间：2025-10-29

- Advances in Chlorinated Poly(vinyl chloride): from Modification to Functional Applications
- Acta Polymerica Sinica Vol. 56, Issue 11, Pages: 1926-1953(2025)
- 作者机构：
  
  1.四川大学高分子研究所先进高分子材料全国重点实验室成都 610065
  2.金发科技股份有限公司广州 510663
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25109
  CLC：
- CSTR：32057.14.GFZXB.2025.7432
- Received：25 April 2025，
  
  Accepted：27 May 2025，
  
  Published Online：26 September 2025，
  
  Published：20 November 2025
- 稿件说明：
移动端阅览
张龙, 柯其宁, 刘乐文, 陈延安, 邹声文, 秦朋, 郭少云. 氯化聚氯乙烯：从改性塑料到功能化应用的研究进展. 高分子学报, 2025, 56(11), 1926-1953

Zhang, L.; Ke, Q. N.; Liu, L. W.; Chen, Y. A.; Zou, S. W.; Qin, P.; Guo, S. Y. Advances in chlorinated poly(vinyl chloride): from modification to functional applications. Acta Polymerica Sinica, 2025, 56(11), 1926-1953
张龙, 柯其宁, 刘乐文, 陈延安, 邹声文, 秦朋, 郭少云. 氯化聚氯乙烯：从改性塑料到功能化应用的研究进展. 高分子学报, 2025, 56(11), 1926-1953 DOI： 10.11777/j.issn1000-3304.2025.25109. CSTR： 32057.14.GFZXB.2025.7432.

Zhang, L.; Ke, Q. N.; Liu, L. W.; Chen, Y. A.; Zou, S. W.; Qin, P.; Guo, S. Y. Advances in chlorinated poly(vinyl chloride): from modification to functional applications. Acta Polymerica Sinica, 2025, 56(11), 1926-1953 DOI： 10.11777/j.issn1000-3304.2025.25109. CSTR： 32057.14.GFZXB.2025.7432.

摘要

氯化聚氯乙烯材料由于其独特的物理化学性能，在工业界和学术研究领域都引起了广泛的研究兴趣. 本文从氯化聚氯乙烯的合成与氯化反应机理、早期作为改性塑料的研究、及近期报道氯化聚氯乙烯的功能化应用研究这3个方面展开综述. 重点回顾了国内外氯化聚氯乙烯材料的发展概况，并介绍了氯化聚氯乙烯通过合金化改性的相关研究进展，及其近期在纤维领域、微孔膜、聚合物电解质及在废弃锂电池中金属回收处理等功能化应用中的研究进展，为相关氯化聚氯乙烯材料的研究工作者，及不同应用领域的科研人员开阔新的研究思路. 最后，本文还对氯化聚氯乙烯材料在未来的发展上做出了相应的展望，以促进氯化聚氯乙烯在上游合成领域及下游应用研究领域的多元化、高质量发展.

Abstract

Chlorinated poly(vinyl chloride) (CPVC)

owing to its unique physicochemical properties

has garnered extensive research interest in both industrial and academic fields. This review systematically summarizes CPVC from three key perspectives: (1) synthesis and chlorination mechanisms

(2) early-stage research as a modified plastic

and (3) recent advances in functional applications. A comprehensive overview of the development of CPVC materials globally

chlorination mechanisms

and typical production process (including solution method

gas-solid phase method

and aqueous suspension method) of CPVC have been briefly introduced. Research on the processing and molding of CPVC was summarized. Studies on the physical blending modification of CPVC with various polymers (such as PVC

ABS

and PMMA) were comprehensively reviewed

while progress in chemical modification via graft copolymerization was briefly presented. Additionally

the pyrolysis behavior

flame retardancy

smoke suppression

and aging resistance of CPVC materials were discussed. More importantly

highlighting progress in emerging functional applications

including CPVC fiber and its derivative carbon fiber

CPVC microporous membranes

CPVC-based solid polymer electrolytes

and metal recovery from spent lithium-ion batteries have been systematically reviewed

which indicates that CPVC play a critical role among multidisciplinary research fields. These insights aim to inspire researchers working on CPVC materials and scientists across various application fields. Finally

in this review

an outlook on the future development of CPVC has been proposed

emphasizing the need for diversification and high-quality advancements in both upstream synthesis and downstream applications.

关键词

Keywords

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