Preparation of Spherical Lignin-sulfoacid Phenolic Resin and Its Adsorption Performance for Rhodamine B

Tao He; Da-zheng Wang; Chun-hong Wang

doi:10.11777/j.issn1000-3304.2025.25260

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Preparation of Spherical Lignin-sulfoacid Phenolic Resin and Its Adsorption Performance for Rhodamine B

Research Article | 更新时间：2026-03-23

- Preparation of Spherical Lignin-sulfoacid Phenolic Resin and Its Adsorption Performance for Rhodamine B
- Acta Polymerica Sinica Vol. 57, Issue 3, Pages: 807-818(2026)
- 作者机构：
  
  南开大学功能高分子材料教育部重点实验室化学学院高分子化学研究所天津 300071
- 作者简介：
  
  Chun-hong Wang, E-mail: wch2004@nankai.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25260
  CLC：
- CSTR：32057.14.GFZXB.2025.7523
- Received：11 October 2025，
  
  Accepted：01 December 2025，
  
  Online First：15 January 2026，
  
  Published：20 March 2026
- 稿件说明：
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何涛, 王大铮, 王春红. 球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究. 高分子学报, 2026, 57(3), 807-818.

He, T.; Wang, D. Z.; Wang, C. H. Preparation of spherical lignin-sulfoacid phenolic resin and its adsorption performance for rhodamine B. Acta Polymerica Sinica (in Chinese), 2026, 57(3), 807-818.
何涛, 王大铮, 王春红. 球形木质素磺酸-酚醛树脂的制备及其对罗丹明B的吸附性能研究. 高分子学报, 2026, 57(3), 807-818. DOI： 10.11777/j.issn1000-3304.2025.25260. CSTR： 32057.14.GFZXB.2025.7523.

He, T.; Wang, D. Z.; Wang, C. H. Preparation of spherical lignin-sulfoacid phenolic resin and its adsorption performance for rhodamine B. Acta Polymerica Sinica (in Chinese), 2026, 57(3), 807-818. DOI： 10.11777/j.issn1000-3304.2025.25260. CSTR： 32057.14.GFZXB.2025.7523.

摘要

针对碱性染料废水处理及木质素高值化利用的双重需求，提出了一种

通过反相悬浮聚合一步制备球形木质素磺酸-酚醛树脂型吸附剂的方法. 通过优化聚合工艺、改变木质素磺酸钠投入量、交联剂及溶剂用量，实现了较高木质素投入量下的树脂球形度和吸附量的调控. 原位聚合引入磺酸基作为吸附位点，有效避免了额外改性步骤并实现了磺酸基较高密度(≥1.24 mmol·g

-1

)的保留与均匀分布. 吸附实验结果表明，所设计的球形木质素磺酸-酚醛树脂型吸附剂在较宽的pH范围内对碱性染料罗丹明B均有较高的吸附能力，吸附量高达2156 mg·g

-1

，远超广泛应用的商品化大孔强酸性树脂D072 (1502 mg·g

-1

)；结果讨论表明，其对罗丹明B的吸附机理主要归因于离子交换、疏水效应及氢键作用，且丰富的孔道结构有利于各吸附机制发挥协同作用，为碱性染料废水处理领域开发与设计高性能应用型木质素基酚醛树脂吸附剂提供了参考.

Abstract

Addressing the dual demands of alkaline dye wastewater treatment and high-value utilization of lignin

this study proposes a one-step suspension polymerization method for the preparation of spherical sodium lignosulfonate-phenolic resin-based adsorbents. By optimizing the polymerization process

adjusting the dosage of sodium lignosulfonate

cross-linking agent

and solvent

the regulation of resin sphericity and adsorption capacity under a relatively high lignin dosage was achieved. Sulfonic acid groups were introduced as adsorption sites through

in situ

polymerization

which effectively eliminated the need for additional modification steps and enabled the retention of a high density (≥1.24 mmol·g

-1

) of sulfonic acid gro

ups with uniform distribution. Adsorption experiments demonstrated that the designed spherical sodium lignosulfonate-phenolic resin-based adsorbents exhibited excellent adsorption capacity for the alkaline dye rhodamine B over a wide pH range

with a maximum adsorption capacity of up to 2156 mg·g

-1

. This value far exceeded that of the widely used commercial macroporous strong acid resin D072 (1502 mg·g

-1

). The discussion of the results indicated that the adsorption mechanism of rhodamine B was mainly attributed to ion exchange

hydrophobic effect and hydrogen bonding

and the abundant pore structure was conducive to the synergistic effect of various adsorption mechanisms. This research provides an important reference for the development and design of high-performance and practical lignin-based phenolic resin adsorbents in the field of basic dye wastewater treatment

and at the same time contributes to the high-value conversion of lignin

a renewable biomass resource.

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Keywords

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