Functionalization of Polydienes by Coordination Polymerization

Jin-liang Liu; Feng Wang; Heng Liu; Xue-quan Zhang

doi:10.11777/j.issn1000-3304.2026.26075

您当前的位置：

首页 >

文章列表页 >

Functionalization of Polydienes by Coordination Polymerization

更新时间：2026-06-17

- Functionalization of Polydienes by Coordination Polymerization
- Acta Polymerica Sinica Pages: 1-25(2026)
- 作者机构：
  
  青岛科技大学高分子科学与工程学院橡塑材料与工程教育部重点实验室青岛 266000
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.26075
  CLC：
- CSTR：32057.14.GFZXB.2026.7614
- Received：13 March 2026，
  
  Accepted：29 April 2026，
  
  Online First：17 June 2026，
- 稿件说明：
移动端阅览
刘金良, 王凤, 刘恒, 张学全. 配位聚合二烯烃橡胶的官能化. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26075.

Liu, J. L.; Wang, F.; Liu, H.; Zhang, X Q. Functionalization of polydienes by coordination polymerization. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26075.
刘金良, 王凤, 刘恒, 张学全. 配位聚合二烯烃橡胶的官能化. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26075. DOI： CSTR： 32057.14.GFZXB.2026.7614.

Liu, J. L.; Wang, F.; Liu, H.; Zhang, X Q. Functionalization of polydienes by coordination polymerization. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26075. DOI： CSTR： 32057.14.GFZXB.2026.7614.

摘要

聚二烯烃橡胶多应用于复杂多组分体系，其分子骨架主要由碳、氢元素组成，整体极性较低. 这一结构特征使其与各类极性填料、助剂等组分的相容性较差，进而限制了材料综合性能的提升与应用范围的拓展. 在聚二烯烃橡胶分子链中引入含杂原子的官能团，可在保留其优异弹性的基础上，显著改善与极性组分间的界面相互作用及相容性，是当前提升聚二烯烃橡胶综合性能、拓宽其应用场景的重要技术途径. 配位聚合能够精准调控聚二烯烃橡胶的链结构与立体构型，是制备高结构规整性橡胶材料的关键方法，已在多种工业橡胶的生产中得到应用. 然而，受杂原子对催化活性中心的毒化作用影响，采用配位聚合法制备官能化聚二烯烃橡胶仍面临较大挑战. 本文系统综述了基于配位聚合路线构筑官能化聚二烯烃橡胶的研究进展，重点归纳出两类主要策略：一是通过共轭二烯烃与含极性官能团的单体直接共聚，在聚合过程中实现官能化；二是基于反应性基团官能化法，利用聚合形成的活性链端与特定小分子试剂反应，实现链端功能化. 同时，总结了不同金属催化体系在调控聚合行为与官能团引入方面的特点，以期为该领域的后续发展提供清晰思路与理论参考.

Abstract

Polydiene rubbers are widely used in complex multicomponent systems. The backbone of polydienes is mainly composed of carbon and hydrogen atoms

resulting in their inherently low polarity

leading to their poor compatibility with various polar fillers

additives

and other components

which consequently limits their overall performance and broader applications. Introducing heteroatom-containing functional groups into the polymer chains can significantly enhance the interfacial interactions and compatibility with polar components

while preserving their excellent elasticity. Therefore

functionalization has recently emerged as an important strategy for improving the comprehensive performance of polydiene rubbers and expanding their potential applications. Coordination polymerization enables p

recise control over the chain microstructure and stereoregularity of polydiene rubbers and has become a key strategy for preparing highly regular rubber materials. This method has also been widely applied in the industrial production of synthetic rubbers. However

the preparation of functionalized polydiene rubbers

via

coordination polymerization remains highly challenging because the heteroatoms in polar functional groups often poison the catalytically active centers. To address these challenges

this review systematically summarizes recent advances in the synthesis of functionalized polydiene rubbers

via

coordination-polymerization strategies. Two main approaches are highlighted: (1) direct copolymerization of conjugated dienes with polar functional comonomers to achieve in-chain functionalization during polymerization

and (2) chain-end functionalization

in which the active chain ends generated during polymerization react with specific small-molecule reagents to introduce functional groups at the chain termini. For the latter

four different methods

including nucleophilic addition

nucleophilic substitution

metal methathesis

and functionalized co-catalyst activation

were employed to incorporate functional groups into the

-end

and both

- and

-ends. In addition

the characteristics of different catalytic systems in regulating polymerization behavior and facilitating functional group incorporation are discussed

with the aim of providing useful insights and theoretical guidance for future developments in this field.

关键词

Keywords

references

张爱民 , 姜连升 , 姜森 , 等 . 合成橡胶技术丛书第六分册配位聚合二烯烃橡胶 , 中国石化出版社 , 北京 , 2016 .

姜连升 . 稀土顺丁橡胶 . 北京 : 冶金工业出版社 , 2016 .

陈文启 , 王佛松 . 稀土络合催化合成橡胶 . 中国科学(B辑) , 2009 ( 10 ), 1006 - 1027 .

钱伯章 . 高端溶聚丁苯橡胶研究获突破 . 石化技术与应用 , 2025 , 43 ( 2 ), 155 .

崔冬梅 . 稀土催化极性单体配位均聚及与非极性单体共聚合的研究 . 高分子学报 , 2020 , 51 ( 1 ), 12 - 29 . doi: 10.11777/j.issn1000-3304.2020.19142 http://dx.doi.org/10.11777/j.issn1000-3304.2020.19142

陈敏 , 陈昶乐 . 官能团化聚烯烃: 新催化剂、新聚合调控手段、新材料 . 高分子学报 , 2018 , ( 11 ), 1372 - 1384 . doi: 10.11777/j.issn1000-3304.2018.18155 http://dx.doi.org/10.11777/j.issn1000-3304.2018.18155

陈敏 , 陈昶乐 . 功能化聚烯烃材料的制备与性质研究 . 高分子通报 , 2021 , 34 ( 6 ), 26 - 34 .

Tang M. Z. ; Zhang R. ; Li S. Q. ; Zeng J. ; Luo M. C. ; Xu Y. X. ; Huang G. S. Towards a supertough thermoplastic polyisoprene elastomer based on a biomimic strategy . Angew. Chem. Int. Ed. , 2018 , 57 ( 48 ), 15836 - 15840 . doi: 10.1002/anie.201809339 http://dx.doi.org/10.1002/anie.201809339

Xu Y. C. ; Zhao J. Y. ; Gan Q. ; Ying W. L. ; Hu Z. H. ; Tang F. M. ; Luo W. W. ; Luo Y. J. ; Jian Z. B. ; Gong D. R. Synthesis and properties investigation of hydroxyl functionalized polyisoprene prepared by cobalt catalyzed co-polymerization of isoprene and hydroxylmyrcene . Polym. Chem. , 2020 , 11 ( 12 ), 2034 - 2043 . doi: 10.1039/c9py01808e http://dx.doi.org/10.1039/c9py01808e

Leicht H. ; Göttker-Schnetmann I. ; Mecking S. Synergetic effect of monomer functional group coordination in catalytic insertion polymerization . J. Am. Chem. Soc. , 2017 , 139 ( 20 ), 6823 - 6826 . doi: 10.1021/jacs.7b03087 http://dx.doi.org/10.1021/jacs.7b03087

Leicht H. ; Göttker-Schnetmann I. ; Mecking S. Stereoselective copolymerization of butadiene and functionalized 1 , 3 -dienes . ACS Macro Lett. 2016, 5 ( 6 ), 777 - 780 . doi: 10.1021/acsmacrolett.6b00321 http://dx.doi.org/10.1021/acsmacrolett.6b00321

Liang S. S. ; Zhang H. Q. ; Cong R. X. ; Liu H. ; Wang F. ; Hu Y. M. ; Zhang X. Q. In-chain functionalized syndiotactic 1 , 2 -polybutadiene by a Ziegler-Natta iron(iii) catalytic system . RSC Adv., 2019, 9 ( 57 ), 33465 - 33471 . doi: 10.1039/c9ra06499k http://dx.doi.org/10.1039/c9ra06499k

Leicht H. ; Huber S. ; Göttker-Schnetmann I. ; Mecking S. Allylboration as a versatile tool for the in situ post-polymerization functionalization of 1 , 4 - cis -poly(butadiene) . Polym. Chem., 2016, 7 ( 47 ), 7195 - 7198 . doi: 10.1039/c6py01388k http://dx.doi.org/10.1039/c6py01388k

Yao C. G. ; Liu N. ; Long S. Y. ; Wu C. J. ; Cui D. M. Highly cis-1 , 4 -selective coordination polymerization of polar 2 -( 4 -methoxyphenyl)-1, 3 -butadiene and copolymerization with isoprene using a β -diketiminato yttrium bis(alkyl) complex . Polym. Chem., 2016, 7 ( 6 ), 1264 - 1270 . doi: 10.1039/c5py01801c http://dx.doi.org/10.1039/c5py01801c

Long S. Y. ; Lin F. ; Yao C. G. ; Cui D. M. Highly cis-1 , 4 selective living polymerization of unmasked polar 2 -( 2 -methylidenebut-3-enyl)furan and Diels-Alder addition . Macromol. Rapid Commun., 2017, 38 ( 17 ), 1700227 .

Thiele S. K. H. ; Wilson D. R. Alternate transition metal complex based diene polymerization . J. Macromol. Sci. Part C , 2003 , 43 ( 4 ), 581 - 628 . doi: 10.1081/mc-120025979 http://dx.doi.org/10.1081/mc-120025979

简忠保 . 功能化聚烯烃合成: 从催化剂到极性单体设计 . 高分子学报 , 2018 , ( 11 ), 1359 - 1371 . doi: 10.11777/j.issn1000-3304.2018.18146 http://dx.doi.org/10.11777/j.issn1000-3304.2018.18146

Gong D. R. ; Tang F. M. ; Xu Y. C. ; Hu Z. H. ; Luo W. W. Cobalt catalysed controlled copolymerization: an efficient approach to bifunctional polyisoprene with enhanced properties . Polym. Chem. , 2021 , 12 ( 11 ), 1653 - 1660 . doi: 10.1039/d1py00101a http://dx.doi.org/10.1039/d1py00101a

Wu H. J. ; Chen B. H. ; Gong D. R. Fabrication and properties study of well-dispersed fillers reinforced cis-1 , 4 polybutadiene composites . ACS Appl. Polym. Mater., 2024, 6 ( 19 ), 11889 - 11900 . doi: 10.1021/acsapm.4c01988 http://dx.doi.org/10.1021/acsapm.4c01988

Wang B. B. ; Liu H. ; Tang T. ; Zhang X. Q. Cis-1 , 4 selective coordination polymerization of 1 , 3 -butadiene and copolymerization with polar 2 - (4-methoxyphenyl)-1, 3 -butadiene by acenaphthene-based α-diimine cobalt complexes featuring intra-ligand π-π stacking interactions. Polymers, 2021, 13 ( 19 ), 3329 . doi: 10.3390/polym13193329 http://dx.doi.org/10.3390/polym13193329

Tang F. M. ; Gong D. R. Polymerization of butadiene , isoprene and 1 -substituted dienes using cobalt catalysts . Inorg. Chim. Acta, 2022, 539 , 121011 . doi: 10.1016/j.ica.2022.121011 http://dx.doi.org/10.1016/j.ica.2022.121011

Cai L. ; Long S. Y. ; Wu C. J. ; Li S. H. ; Yao C. G. ; Hua X. F. ; Na H. ; Liu D. T. ; Tang T. ; Cui D. M. Highly selective cis-1 , 4 copolymerization of dienes with polar 2 -(3pyridine-methylidenepent-4-en-1-yl): an approach for recyclable elastomers . Polym. Chem., 2020, 11 ( 9 ), 1646 - 1652 . doi: 10.1039/c9py01811e http://dx.doi.org/10.1039/c9py01811e

Zhong Y. H. ; Wang B. L. ; Cui D. M. The yttrium-catalyzed heteroatom-assisted terpolymerization of ortho-alkoxystyrene, isoprene and butadiene with high regio- and stereoselectivity . Polym. Chem. , 2021 , 12 ( 31 ), 4576 - 4582 . doi: 10.1039/d1py00840d http://dx.doi.org/10.1039/d1py00840d

Leicht H. ; Göttker-Schnetmann I. ; Mecking S. Stereoselective copolymerization of butadiene and functionalized 1 , 3 -dienes with neodymium-based catalysts . Macromolecules, 2017, 50 ( 21 ), 8464 - 8468 . doi: 10.1021/acs.macromol.7b02007 http://dx.doi.org/10.1021/acs.macromol.7b02007

Leicht H. ; Bauer J. ; Göttker-Schnetmann I. ; Mecking S. Heterotelechelic and in-chain polar functionalized stereoregular poly(dienes) . Macromolecules , 2018 , 51 ( 3 ), 763 - 770 . doi: 10.1021/acs.macromol.7b02006 http://dx.doi.org/10.1021/acs.macromol.7b02006

Ling F. W. ; Luo M. C. ; Chen M. K. ; Zeng J. ; Li S. Q. ; Yin H. B. ; Wu J. R. ; Xu Y. X. ; Huang G. S. Terminally and randomly functionalized polyisoprene lead to distinct aggregation behaviors of polar groups . Polymer , 2019 , 178 , 121629 . doi: 10.1016/j.polymer.2019.121629 http://dx.doi.org/10.1016/j.polymer.2019.121629

Sun S. R. ; Tang F. M. ; Gong D. R. Fabrication of cis-1 , 4 polyisoprene composites reinforced with well-dispersed silica/carbon black promoted by silica-rubber hydrogen-bonding . Polym. Compos., 2025, 46 ( 7 ), 6070 - 6082 . doi: 10.1002/pc.29343 http://dx.doi.org/10.1002/pc.29343

Lyubov D. M. ; Tolpygin A. O. ; Trifonov A. A. Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters . Coord. Chem. Rev. , 2019 , 392 , 83 - 145 . doi: 10.1016/j.ccr.2019.04.013 http://dx.doi.org/10.1016/j.ccr.2019.04.013

Yasuda H. ; Ihara E. Rare earth metal initiated polymerizations of polar and nonpolar monomers to give high molecular weight polymers with extremely narrow molecular weight distribution . Macromol. Chem. Phys. , 1995 , 196 ( 8 ), 2417 - 2441 . doi: 10.1002/macp.1995.021960802 http://dx.doi.org/10.1002/macp.1995.021960802

Yasuda H. ; Furo M. ; Yamamoto H. ; Nakamura A. ; Miyake S. ; Kibino N. New approach to block copolymerizations of ethylene with alkyl methacrylates and lactones by unique catalysis with organolanthanide complexes . Macromolecules , 1992 , 25 ( 19 ), 5115 - 5116 . doi: 10.1021/ma00045a045 http://dx.doi.org/10.1021/ma00045a045

Yasuda H. Rare-earth-metal-initiated polymerizations of (meth)acrylates and block copolymerizations of olefins with polar monomers . J. Polym. Sci. Part A Polym. Chem. , 2001 , 39 ( 12 ), 1955 - 1959 . doi: 10.1002/pola.1172 http://dx.doi.org/10.1002/pola.1172

Desurmont G. ; Tanaka M. ; Li Y. ; Yasuda H. ; Tokimitsu T. ; Tone S. ; Yanagase A. New approach to block copolymerization of ethylene with polar monomers by the unique catalytic function of organolanthanide complexes . J. Polym. Sci. Part A Polym. Chem. , 2000 , 38 ( 22 ), 4095 - 4109 . doi: 10.1002/1099-0518(20001115)38:22<4095::aid-pola100>3.0.co;2-r http://dx.doi.org/10.1002/1099-0518(20001115)38:22<4095::aid-pola100>3.0.co;2-r

Desurmont G. ; Tokimitsu T. ; Yasuda H. First controlled block copolymerizations of higher 1-olefins with polar monomers using metallocene type single component lanthanide initiators . Macromolecules , 2000 , 33 ( 21 ), 7679 - 7681 . doi: 10.1021/ma000679r http://dx.doi.org/10.1021/ma000679r

Friebe L. ; Nuyken O. ; Windisch H. ; Obrecht W. In situ preparation of a compatibilized poly(cis-1 , 4 -butadiene)/poly(ε-caprolactone) blend . Macromol. Mater. Eng., 2003, 288 ( 6 ), 484 - 494 . doi: 10.1002/mame.200390045 http://dx.doi.org/10.1002/mame.200390045

Wang L. F. ; Cui D. M. ; Hou Z. M. ; Li W. ; Li Y. Highly cis-1 , 4 -selective living polymerization of 1, 3 -conjugated dienes and copolymerization with ε-caprolactone by bis(phosphino)carbazolide rare-earth-metal complexes . Organometallics, 2011, 30 ( 4 ), 760 - 767 . doi: 10.1021/om1009395 http://dx.doi.org/10.1021/om1009395

Yao C. G. ; Liu D. T. ; Li P. ; Wu C. J. ; Li S. H. ; Liu B. ; Cui D. M. Highly 3 , 4 -selective living polymerization of isoprene and copolymerization with ε -caprolactone by an amidino N-heterocyclic carbene ligated lutetium bis(alkyl) complex . Organometallics, 2014, 33 ( 3 ), 684 - 691 . doi: 10.1021/om400925a http://dx.doi.org/10.1021/om400925a

Fan C. L. ; Bai C. X. ; Cai H. G. ; Dai Q. Q. ; Zhang X. Q. ; Wang F. S. Preparation of high cis-1 , 4 polyisoprene with narrow molecular weight distribution via coordinative chain transfer polymerization . J. Polym. Sci. Part A Polym. Chem., 2010, 48 ( 21 ), 4768 - 4774 . doi: 10.1002/pola.24268 http://dx.doi.org/10.1002/pola.24268

Wang F. ; Liu H. ; Zheng W. J. ; Guo J. ; Zhang C. Y. ; Zhao L. P. ; Zhang H. X. ; Hu Y. M. ; Bai C. X. ; Zhang X. Q. Fully-reversible and semi-reversible coordinative chain transfer polymerizations of 1 , 3 -butadiene with neodymium-based catalytic systems . Polymer, 2013, 54 ( 25 ), 6716 - 6724 . doi: 10.1016/j.polymer.2013.10.031 http://dx.doi.org/10.1016/j.polymer.2013.10.031

Wang F. ; Zhang C. Y. ; Hu Y. M. ; Jia X. Y. ; Bai C. X. ; Zhang X. Q. Reversible coordinative chain transfer polymerization of isoprene and copolymerization with ε-caprolactone by neodymium-based catalyst . Polymer , 2012 , 53 ( 26 ), 6027 - 6032 . doi: 10.1016/j.polymer.2012.10.044 http://dx.doi.org/10.1016/j.polymer.2012.10.044

Wang F. ; Dong B. ; Liu H. ; Guo J. ; Zheng W. J. ; Zhang C. Y. ; Zhao L. P. ; Bai C. X. ; Hu Y. M. ; Zhang X. Q. Synthesis of block copolymers containing polybutadiene segments by combination of coordinative chain transfer polymerization , ring-opening polymerization, and atom transfer radical polymerization. Macromol. Chem. Phys., 2015 , 216 ( 3 ), 321 - 328 . doi: 10.1002/macp.201400465 http://dx.doi.org/10.1002/macp.201400465

Zhang M. M. ; Liu L. J. ; Cong R. X. ; Dong J. ; Wu G. F. ; Wang F. ; Liu H. ; Zhang X. Q. In-situ block copolymerization of 1 , 3 -butadiene with cyclohexene oxide and trimethylene carbonate via combination of coordinative chain transfer polymerization and ring opening polymerization by neodymium-based catalyst system . Eur. Polym. J., 2021, 148 , 110355 . doi: 10.1016/j.eurpolymj.2021.110355 http://dx.doi.org/10.1016/j.eurpolymj.2021.110355

郑荣华 , 张一烽 , 沈之荃 . 异戊二烯/甲基丙烯酸甲酯嵌段共聚物的合成与微结构研究 . 高分子学报 , 1999 , ( 1 ), 107 - 112 .

胡志国 , 张一烽 , 郑荣华 , 沈之荃 . 异戊二烯/丙烯腈嵌段共聚物的合成和性能研究 . 高分子材料科学与工程 , 2002 , 18 ( 3 ), 57 - 60 . doi: 10.3321/j.issn:1000-7555.2002.03.013 http://dx.doi.org/10.3321/j.issn:1000-7555.2002.03.013

张一烽 , 郑荣华 , 沈之荃 . 稀土配位催化异戊二烯与环氧氯丙烷嵌段共聚 . 科学通报 , 1995 , 40 ( 9 ), 795 - 798 .

Kularatne R. N. ; Yang A. N. ; Nguyen H. Q. ; McCandless G. T. ; Stefan M. C. Neodymium catalyst for the polymerization of dienes and polar vinyl monomers . Macromol. Rapid Commun. , 2017 , 38 ( 19 ), 1700427 . doi: 10.1002/marc.201700427 http://dx.doi.org/10.1002/marc.201700427

君轩 . 反式异戊橡胶 . 世界橡胶工业 , 2009 , 36 ( 3 ), 48 - 49 .

Gromada J. ; le Pichon L. ; Mortreux A. ; Leising F. ; Carpentier J. F. Neodymium alk(aryl)oxides-dialkylmagnesium systems for butadiene polymerization and copolymerization with styrene and glycidyl methacrylate . J. Organomet. Chem. , 2003 , 683 ( 1 ), 44 - 55 . doi: 10.1016/s0022-328x(03)00380-2 http://dx.doi.org/10.1016/s0022-328x(03)00380-2

Zheng W. J. ; Yan N. ; Zhu Y. T. ; Zhao W. P. ; Zhang C. Y. ; Zhang H. X. ; Bai C. X. ; Hu Y. M. ; Zhang X. Q. Highly trans-1 , 4 -stereoselective coordination chain transfer polymerization of 1, 3 -butadiene and copolymerization with cyclic esters by a neodymium-based catalyst system . Polym. Chem., 2015, 6 ( 33 ), 6088 - 6095 . doi: 10.1039/c5py00877h http://dx.doi.org/10.1039/c5py00877h

Barbier-Baudry D. ; Bonnet F. ; Dormond A. ; Finot E. ; Visseaux M. Diene/polar monomer copolymers, compatibilisers for polar/non-polar polymer blends . a controlled block copolymerisation with a single-site component samarocene initiator. Macromol. Chem. Phys. , 2002 , 203 ( 9 ), 1194 - 1200 . doi: 10.1002/1521-3935(200206)203:9<1194::aid-macp1194>3.0.co;2-8 http://dx.doi.org/10.1002/1521-3935(200206)203:9<1194::aid-macp1194>3.0.co;2-8

Wang J. X. ; Xu S. T. ; Hu X. ; Huo Y. C. ; Shi X. C. Rare-earth metal complexes bearing pyridyl-functionalized amidinate ligands for highly trans-1 , 4 -selective living (co)polymerization of 1, 3 -conjugated dienes . Organometallics, 2022, 41 ( 2 ), 115 - 123 . doi: 10.1021/acs.organomet.1c00557 http://dx.doi.org/10.1021/acs.organomet.1c00557

Shi Z. H. ; Guo F. ; Meng R. ; Jiang L. ; Li Y. Stereoselective copolymerization of amino-functionalized styrene with butadiene using a half-sandwich scandium complex . Polym. Chem. , 2016 , 7 ( 48 ), 7365 - 7369 . doi: 10.1039/C6PY01562J http://dx.doi.org/10.1039/C6PY01562J

Fu T. T. ; Jiang L. ; Sun H. Y. ; Hou Z. M. ; Guo F. Scandium-catalyzed stereoselective block and alternating copolymerization of diphenylphosphinostyrenes and isoprene . Polym. Chem. , 2022 , 13 ( 23 ), 3498 - 3505 . doi: 10.1039/d2py00290f http://dx.doi.org/10.1039/d2py00290f

Li S. Q. ; Tang M. Z. ; Huang C. ; Zhang R. ; Wu J. R. ; Ling F. W. ; Xu Y. X. ; Huang G. S. Branching function of terminal phosphate groups of polyisoprene chain . Polymer , 2019 , 174 , 18 - 24 . doi: 10.1016/j.polymer.2019.04.046 http://dx.doi.org/10.1016/j.polymer.2019.04.046

Yao Y. F. ; Zhao Y. H. ; Xie M. J. ; Yang Y. ; Wang X. ; Xu F. ; Xu Y. X. New insights into the strengthening mechanism of nanofillers in terminally functionalized polyisoprene rubbers . Ind. Eng. Chem. Res. , 2025 , 64 ( 7 ), 4073 - 4084 . doi: 10.1021/acs.iecr.4c02989 http://dx.doi.org/10.1021/acs.iecr.4c02989

Wang W. X. ; Zhao W. P. ; Dong J. ; Zhang H. Q. ; Wang F. ; Liu H. ; Zhang X. Q. Polyisoprene bearing dual functionalized mini-blocky chain-ends prepared from neodymium-mediated coordinative chain transfer polymerizations . Chin. J. Polym. Sci. , 2023 , 41 ( 5 ), 720 - 727 . doi: 10.1007/s10118-023-2953-z http://dx.doi.org/10.1007/s10118-023-2953-z

王卫鑫 , 赵文朋 , 董静 , 王凤 , 张学全 , 刘恒 . 高1,4-结构的双端多羟基液体聚丁二烯橡胶的制备 . 高分子学报 , 2025 , 56 ( 3 ), 457 - 464 .

Sun Y. F. ; Zhao Y. N. ; Xu S. L. ; Yu Y. ; Fang L. ; Na L. H. ; Yang Q. ; Wang F. ; Liu H. ; Zhang C. Y. ; Zhang X. Q. Synthesis and characterization of α-end functionalized 3 , 4 -polyisoprene using Fe(acac) 3 /IITP/AliBu 3 catalyst . Chinese J. Polym. Sci., 2025, 43 ( 8 ), 1367 - 1374 . doi: 10.1007/s11270-023-06813-8 http://dx.doi.org/10.1007/s11270-023-06813-8

黄贵秋 . 稀土催化丁二烯聚合过程中的末端改性 . 精细石油化工 , 2012 , 29 ( 6 ), 21 - 24 .

崔小明 . 稀土催化丁二烯聚合过程中的末端改性 . 橡胶科技 , 2013 , 11 ( 12 ), 57 .

Hattori I. ; Sakakibara M. ; Tsutsumi F. ; Yoshizawa M. Preparation of conjugated diene polymers modified with an organo- tin or germanium halide . US Patent , US 5064910 . 1991-11-12.

Hattori I. ; Sakakibara M. ; Tsutsumi F. ; Yoshizawa M. Modified conjugated diene polymer and process for production thereof . European Patent , EP 0267675 A 2 . 1988-05-18 .

Sone T. ; Nonaka K. ; Hattori I. ; Takashima , A Method for producing conjugated diene polymers . European Patent , EP 0863165 A 1 . 1998-09-09 .

Andreussi P. ; Bianchi R. ; Bruzzone M. Method for preparing polybutadiene endowed with improved processability characteristics . European Patent , EP 0386808 A 1 . 1990-09-12 .

Hattori I. ; Tsutsumi F. ; Sakakibara M. ; Makino K. Modification of neodymium high cis-1 , 4 polybutadiene with tin compounds . J. Elastomers Plast., 1991, 23 ( 2 ), 135 - 151 . doi: 10.1177/009524439102300205 http://dx.doi.org/10.1177/009524439102300205

Sone T. ; Hattori I. ; Yamazaki D. ; Nonaka K. Method for producing conjugated diene polymers with narrow molecular weight distribution and polymer produced thereby . European Patent , EP 1099710 B 1 . 2005-01-19 .

Ozawa Y. ; Miller H. J. ; Masaki K. ; Fujimaki T. ; Sone T. ; Hattori I. ; Morita K. Modified polymers prepared with lanthanide- based catalysts . WO 01 / 34658 . 2001-05-17 .

Hattori I. ; Yasuda K. ; Sakakibara M. ; Makino K. Chemical modification of neodymium high cis-1 , 4 polybutadiene with styreneoxide . Polym. Adv. Technol., 1993, 4 ( 7 ), 450 - 456 . doi: 10.1002/pat.1993.220040708 http://dx.doi.org/10.1002/pat.1993.220040708

Tanaka R. ; Sone T. ; Tadaki T. Modified conjugated diene polymer and process for producing the same . US Patent , US 2005009979 A 1 . 2005-01-13 . doi: 10.1201/9780367694265-eppmpt131-1 http://dx.doi.org/10.1201/9780367694265-eppmpt131-1

Dong K. X. ; Zhang J. Y. ; He A. H. Synthesis of amine-capped trans-1 , 4 -polyisoprene . Polymer, 2021, 235 , 124231 . doi: 10.1016/j.polymer.2021.124231 http://dx.doi.org/10.1016/j.polymer.2021.124231

Kwag G. ; Kim A. ; Lee S. Method of preparation of siloxane- functionalized high 1 , 4 -cis polybutadiene . US Patent, US 20020137843 A 1 . 2002-09-26 . doi: 10.5254/1.3547691 http://dx.doi.org/10.5254/1.3547691

Fujimaki T. ; Ito K. Modified conjugated diene copolymer , process for producing the same, and composition thereof. European Patent, EP 0713885 A 1 . 1996-05-29 .

Morita K. ; Iwata T. Modified conjugated diene polymer and process for producing the same . Japanese Patent , JP 2001098015 A. 2001-04-10 .

Ozawa Y. ; Miller H. J. ; Masaki K. ; Morita K. ; Fujimaki T. ; Omura T. ; Sone T. ; Hattori I. Modified polymers prepared with lanthanide-based catalysts . WO 2002038615 A 1 . 2002-05-16 .

Georges S. ; Hashmi O. H. ; Bria M. ; Zinck P. ; Champouret Y. ; Visseaux M. Efficient one-pot synthesis of end-functionalized trans -stereoregular polydiene macromonomers . Macromolecules , 2019 , 52 ( 3 ), 1210 - 1219 . doi: 10.1021/acs.macromol.8b01520 http://dx.doi.org/10.1021/acs.macromol.8b01520

张荣 , 唐茂株 , 李世其 , 徐云祥 , 黄光速 . 端基寡肽对不同分子量聚异戊二烯性能的影响 . 合成橡胶工业 , 2018 , 41 ( 4 ), 266 - 270 .

曾建 , 李世其 , 黄光速 , 徐云祥 . 端基四肽聚异戊二烯的合成表征及流变性能 . 高分子材料科学与工程 , 2017 , 33 ( 7 ), 1 - 5 . doi: 10.16865/j.cnki.1000-7555.2017.07.001 http://dx.doi.org/10.16865/j.cnki.1000-7555.2017.07.001

Luo S. ; Yan Y. Y. ; Poulton J. T. ; Suzuki E. Preparation of functionalized diene polymers using rare earth catalyst systems . US Patent , US 20080146745 A 1 . 2008-06-19 .

Ozawa Y. ; Miller H. J. ; Masaki K. Modified polymers prepared with lanthanide-based catalysts . WO 0134659 A 1 . 2001-05-17 .

Tanaka R. ; Kuwabara Y. ; Nakayama Y. ; Shiono T. Synthesis of chain-end functional polydienes using diene comonomer bearing boronic acid masked with diaminonaphthalene . Molecules , 2022 , 27 ( 24 ), 9007 . doi: 10.3390/molecules27249007 http://dx.doi.org/10.3390/molecules27249007

Zheng Y. Y. ; Zhu H. ; Huang X. C. ; Wu Y. X. Amphiphilic silicon hydroxyl-functionalized cis -polybutadiene: synthesis , characterization, and properties. Macromolecules, 2021 , 54 ( 5 ), 2427 - 2438 . doi: 10.1021/acs.macromol.0c02697 http://dx.doi.org/10.1021/acs.macromol.0c02697

Göttker-Schnetmann I. ; Kenyon P. ; Mecking S. Coordinative chain transfer polymerization of butadiene with functionalized aluminum reagents . Angew. Chem. Int. Ed. , 2019 , 58 ( 49 ), 17777 - 17781 . doi: 10.1002/anie.201909843 http://dx.doi.org/10.1002/anie.201909843

Zhang X. H. ; Dong J. ; Wang F. ; Zhang X. Q. ; Liu H. In situ efficient end functionalization of polyisoprene by epoxide compounds via neodymium-mediated coordinative chain transfer polymerization . Polymers , 2024 , 16 ( 18 ), 2672 . doi: 10.3390/polym16182672 http://dx.doi.org/10.3390/polym16182672

张秀慧 , 董静 , 王凤 , 刘恒 , 张学全 . 用配位可逆链转移体系原位制备末端官能化聚二烯烃橡胶 . 合成橡胶工业 , 2024 , 47 ( 4 ), 347 .

张秀慧 , 董静 , 李伟天 , 李旭 , 王凤 , 刘恒 , 张学全 . 高分子量端酰胺官能化顺丁橡胶的合成与性能研究 . 高分子学报 , 2025 , 56 ( 9 ), 1633 - 1643 .

Wu Y. ; Nan T. H. ; Ji X. L. ; Liu B. ; Cui D. M. A facile approach to produce star polymers based on coordination polymerization . Angew. Chem. Int. Ed. , 2022 , 61 ( 29 ), e 202205894 . doi: 10.1002/anie.202205894 http://dx.doi.org/10.1002/anie.202205894

Luo S. F. ; Dong K. X. ; Wang S. ; He A. H. Synergistic enhancement of magic triangle properties of PC tread stocks modified by amine-capped trans-1 , 4 -poly(butadiene-co-isoprene) . Compos. Sci. Technol., 2024, 258 , 110899 . doi: 10.1016/j.compscitech.2024.110899 http://dx.doi.org/10.1016/j.compscitech.2024.110899

王凤 , 张贺新 , 白晨曦 , 张学全 . 双烯烃配位链转移聚合研究进展 . 高分子通报 , 2014 , 27 ( 5 ), 57 - 64 .

Wang F. ; Liu H. ; Hu Y. M. ; Zhang X. Q. Lanthanide complexes mediated coordinative chain transfer polymerization of conjugated dienes . Sci. China Technol. Sci. , 2018 , 61 ( 9 ), 1286 - 1294 . doi: 10.1007/s11431-018-9256-6 http://dx.doi.org/10.1007/s11431-018-9256-6

Zhang H. D. ; Zhang X. H. ; Zheng H. ; Wang F. ; Wei X. D. ; Zhang X. Q. ; Liu H. Synthesis of α , ω -end hetero-functionalized polyisoprene via neodymium-mediated coordinative chain transfer polymerization . Polym. Chem. , 2025 , 16 ( 14 ), 1556 - 1567 . doi: 10.1039/d4py01452a http://dx.doi.org/10.1039/d4py01452a

Zheng H. ; Zhang H. D. ; Zhao W. P. ; Wang F. ; Zhang X. Q. ; Liu H. Controllable preparation of hydroxyl-terminated liquid polydiene rubber featuring high 1 , 4 -content by neodymium-mediated coordinative chain transfer polymerizations strategy . J. Appl. Polym. Sci., 2025, 142 ( 41 ), e 57602 . doi: 10.1002/app.57602 http://dx.doi.org/10.1002/app.57602

Liu P. B. ; Yang X. ; Li H. ; Zhang S. B. ; Hu Y. M. ; Zhou G. Y. ; Hadjichristidis N. Synthesis of α , ω -end functionalized polydienes: allylic-bearing heteroleptic aluminums for selective alkylation and transalkylation in coordinative chain transfer polymerization . Angew. Chem. Int. Ed. , 2024 , 63 ( 5 ), e 202317494 . Review. doi: 10.1002/anie.202317494 http://dx.doi.org/10.1002/anie.202317494

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Amino-functionalization of Ethylene-Propylene Rubber and Its Dynamic Cross-linking

Synthesis and Performance Study of High-molecular-weight Amide End-functionalized cis-Polybutadiene Rubber

N-Bridged Phosphine Carbonyl Palladium Complex Catalysts for Nonalternating Copolymerization of Ethylene and Carbon Monoxide

Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts

Heterogeneous Fluorenylamidodimethyltitanium Catalyzed α-Olefin Polymerization

Related Author

Peng-fei Cao

Teng Wang

Shang-tao Chen

Zhen-hao Guo

Guang-yu Li

Tian-xiao Chang

Chang Sun

Xu Li

Related Institution

State Key Laboratory of Organic-Inorganic Composites, School of Materials Science and Engineering

School of College of Chemistry, Beijing University of Chemical Technology

PetroChina Petrochemical Research Institute

Key Laboratory of Rubber-Plastics of Ministry of Education, Shandong Provincial Key Laboratory of Rubber-Plastics, School of Polymer Science and Engineering, Qingdao University of Science and Technology

Lanzhou Petrochemical Research Center, Pretrochemical Research Institute, Petro China Co. Ltd.

AI问答

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802046899号
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰