A method for chemically attaching ultra-thin polymer films through the self-assembly of end silane terminated polymer is provided in this article．End trimethoxysilane functionalized polystyrene (PSt) was first prepared through radical chain transfer reaction and characterized by FTIR

1H-NMR and gel permeation chromatography (GPC)．The coincidence of the calculated molecular weight of the prepared end silane terminated PSt from both GPC and NMR proved high end functionalized ratio．The self-assembly behavior on silicon wafers of the obtained polymer was studied by measuring the contact angle

film thickness．The chemical characteristics and the nano scale morphology of the film were investigated with FTIR

X-ray photoelectro spectroscopy (XPS)

atomic force microscopy (AFM)．It was found that homogeneous and complete polymer film could be formed only when the polymer concentration exceeded 1 mg／mL．The root mean roughness of the complete polymer was below 1 nm．The tribological properties of the prepared PSt film were investigated using a static-dynamic friction precision measurement apparatus．The friction coefficient of self-assembled PSt film against steel ball at a load of 0.5 N was in the range of 0.08～0.1 which was much lower than that for bare silicon wafers in the same experiment conditions (0.7～0.8)．Self assembled PSt modified silicon wafers exhibited excellent friction reduction and anti-wear behavior comparing with their bare counterparts．According to this investigation

serf-assembled polymer films have the prospect for friction reduction and wear resistance．