N-[4-(磺酰胺)苯基]丙烯酰胺与丙烯腈、甲基丙烯酸甲酯共聚合的竞聚率

高英新; 包永忠; 黄志明; 翁志学

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N-[4-(磺酰胺)苯基]丙烯酰胺与丙烯腈、甲基丙烯酸甲酯共聚合的竞聚率

研究简报 | 更新时间：2021-03-19

- N-[4-(磺酰胺)苯基]丙烯酰胺与丙烯腈、甲基丙烯酸甲酯共聚合的竞聚率
- REACTIVITY RATIOS OF N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE/ACRYLONITRILE AND N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE/METHYL METHACRYLATE COPOLYMERIZATION SYSTEMS
- 高分子学报 2004年第3期页码：450-453
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- 纸质出版日期：2004-6-20，
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高英新, 包永忠, 黄志明, 翁志学. N-[4-(磺酰胺)苯基]丙烯酰胺与丙烯腈、甲基丙烯酸甲酯共聚合的竞聚率[J]. 高分子学报, 2004,(3):450-453.

GAO Yingxin, BAO Yongzhong, HUANG Zhiming, WENG Zhixue. REACTIVITY RATIOS OF N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE/ACRYLONITRILE AND N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE/METHYL METHACRYLATE COPOLYMERIZATION SYSTEMS[J]. Acta Polymerica Sinica, 2004,(3):450-453.
高英新, 包永忠, 黄志明, 翁志学. N-[4-(磺酰胺)苯基]丙烯酰胺与丙烯腈、甲基丙烯酸甲酯共聚合的竞聚率[J]. 高分子学报, 2004,(3):450-453. DOI：

GAO Yingxin, BAO Yongzhong, HUANG Zhiming, WENG Zhixue. REACTIVITY RATIOS OF N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE/ACRYLONITRILE AND N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE/METHYL METHACRYLATE COPOLYMERIZATION SYSTEMS[J]. Acta Polymerica Sinica, 2004,(3):450-453. DOI：

摘要

Abstract

N-[4-(aminosulfonyl)phenyl]acrylamide (ASPAA) was synthesized through the reaction of acryloyl chloride with sulfanilamide

and copolymefized with acrylonitrile (AN) and metbyl methacrylate (MMA)

respeetivety．in DMF solvent using benzoyl peroxide as initiator at(70±0.5)℃．The copolymer composition was determined by using elemental analysis and the reactivity ratios of ASPAA/AN and ASPAA/MMA copolymerization systems were calculated by employing the Fineman-Ross and the Kelen-Tudos methods．The values of r1 and r2 obtained by the two methods fitted well with each other

i．e．r1(ASPAA)=1.43

r2(AN)=0.44 by Fineman-Ross method and r1(ASPAA)=1.39

r2(AN)=0.43 by Kelen-Tudos method for ASPAA/AN copolymerization system

and

r1(ASPAA)=0.88

r2(MMA)=1.42 by Fineman-Ross method and r1(ASPAA)=0.83

r2(AN)=1.35 by Kelen-Tudos method for ASPAA/MMA copolymefization system．

关键词

N-[4-（磺酰胺）苯基]丙烯酰胺丙烯腈甲基丙烯酸甲酯共聚竞聚率

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