KE Linping, GUO Meili, ZHAO Delu. DETERMINING MOLECULAR WEIGHT DISTRIBUTION INDEX FROM FLOW CURVES FOR POLYPROPYLENE[J]. Acta Polymerica Sinica, 2004,(3):442-445.
KE Linping, GUO Meili, ZHAO Delu. DETERMINING MOLECULAR WEIGHT DISTRIBUTION INDEX FROM FLOW CURVES FOR POLYPROPYLENE[J]. Acta Polymerica Sinica, 2004,(3):442-445.DOI:
A method determining molecular weight distribution index D (MWD) from viscosity versus shear stress flow curves for polypropylene has been presented.Based on the experimental data
the correlation between the viscosity η of molten polypropylene and its MWD can be expressed as η/ηo={1+α(τD)m}-1
where ηo is the zero shear viscosity
τ is the shear stress
α and m are empirical parameters Furthermore
a simpler method to estimate the MWD from only two experimental data
i.e.the melt index (MI) and the zero shear viscosity has also been presented
the calculated results are in good agreement with the data from GPC measurements.