WANG Zhong, SHI Zuoqing, SHI Rongfu, FAN Yunge, YANG Yizhong. THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT[J]. Acta Polymerica Sinica, 2004,(1):64-69.
WANG Zhong, SHI Zuoqing, SHI Rongfu, FAN Yunge, YANG Yizhong. THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT[J]. Acta Polymerica Sinica, 2004,(1):64-69.DOI:
The adsorption of VB12 was studied by usingthree phenolic resin adsorbents:JDW-1
JDW-2
preparedin the laboratory and a commercial product Duolite S-761 under static and dymanic conditions.The experimental results show that JDW-1 is superior to Duolite S-761 in adsorption of VB12(the saturation adsorption capacity of JDW-1 for VB12 is 84 mg/g dried resin).A semi-empirical rate equation adequately fits the sorption rate data of VB12 in the initial period.till about 43%~69% of the equilibrium adsorption.The equilibrium adsorption date for phenolic resin adsorbents/VB12 systems showed good agreement with the Langmuir isotherm equation.The correlation coefficients are larger than 0.99 The adsorption of VB12 therefore is monomolecular adsorption.Experiments of stripping VB12 from JDW-2 resin with 80% aqueous methoanol showed that 92.20%and 95.93% of the adsorbed VB12 were removed at 4.2 and 6.4 bed volumes
respectively
(the desorption rate was 1.1 BV/h).It implies that phenolic resin adsorbents own excellent desorption performance
and it is good to use 80% aqueous methanol as desorption solvent for stripping VBl2 from JDW-2