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研究简报 | 更新时间:2021-03-19
    • 制备方法对iPP/EPR合金晶相结构的影响

    • EFFECT OF PREPARATION METHODS ON CRYSTALLINE STRUCTURE OF iPP/EPR BLENDS

    • 上官勇刚

      ,  

      陶礼阳

      ,  

      赵丽

      ,  

      郑强

      ,  
    • 高分子学报   2007年第8期 页码:770-774
    • 纸质出版日期:2007-8-20

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  • 上官勇刚, 陶礼阳, 赵丽, 郑强. 制备方法对iPP/EPR合金晶相结构的影响[J]. 高分子学报, 2007,(8):770-774. DOI:

    SHANGGUAN Yonggang, TAO Liyang, ZHAO Li, ZHENG Qiang. EFFECT OF PREPARATION METHODS ON CRYSTALLINE STRUCTURE OF iPP/EPR BLENDS[J]. Acta Polymerica Sinica, 2007,(8):770-774. DOI:

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    摘要

    用示差扫描量热仪(DSC)和广角X射线衍射仪(WAXD)研究了溶液共混法和熔融共混法制备的等规聚丙烯/二元乙丙橡胶(iPP/EPR)(85∶15,W/W)合金的晶相结构.发现溶液共混法制得的iPP/EPR合金晶相中仅存在α-iPP,而熔融共混样品中则同时生成了α-iPP和β-iPP.这一结果表明,EPR并不是iPP/EPR合金中β-iPP生成的关键因素.考察了结晶温度和熔体热处理对iPP/EPR合金晶相结构的影响,发现通常的热处理并不能消除合金中β-iPP的生成.

    Abstract

    The crystalline structure of isotactic polypropylene/ ethylene-propylene rubber (iPP/EPR,85∶15,W/W) blends prepared by melt-blending and solution-blending methods,respectively was studied by using modulated differential scanning calorimetry (MDSC) and wide angle X-ray diffraction (WAXD).The experimental results reveal that α-iPP and β-iPP coexist in the PP85m sample prepared by melt-blending method,but only α-iPP appeared in the PP85s sample prepared by solution-blending method,and its crystalline structure is independent on isothermal crystallization temperature.The β-iPP content in PP85m is dependent on the crystallization temperature and approaches to a maximum at about 125℃.In addition,it is found that the iPP/EPR samples experienced annealing at 200℃ for different times(5~30 min)demonstrate the same melting behavior,indicating that the annealing treatment for different times at 200℃ has little effect on the formation of β-iPP in PP85m samples.It is suggested that the formation of β-iPP in PP/EPR blends is dependent on its thermomechanical history.

    关键词

    等规聚丙烯/乙丙橡胶合金; 晶相结构; 制备方法

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