浏览全部资源
扫码关注微信
纸质出版日期:1998-6-20,
扫 描 看 全 文
詹茂盛, 成泽郁夫. 尼龙-6和尼龙-6合金的球晶结构与破坏性能的研究[J]. 高分子学报, 1998,(3):317-323.
ZHAN Maosheng, NARISAWA Ikuo. THE EFFECT OF SPHERULIE CRYSTAL ON PROPERTIES OF TENSILE FRACTURE OF NYLON 6 AND NYLON 6 ALLOY[J]. Acta Polymerica Sinica, 1998,(3):317-323.
成型冷却速度即结晶速度对单纯尼龙-6和尼龙-6合金的拉伸破坏性能具有不同的影响.结晶速度慢
球晶尺寸大
单纯尼龙-6的拉伸破坏强度高
破坏形变和破坏能量减小;尼龙-6/热塑性聚酰胺弹性体/增容剂合金不仅拉伸破坏强度高
而且破坏形变和破坏能量都有所增加.研究表明
虽然球晶尺寸影响尼龙-6的破坏性能
但球晶的性质即球晶的界面上和片晶片晶间的非晶部分结构、微小分散粒子的空洞化及相与相之间的界面结合强度是影响尼龙-6破坏性能的主要因素.
The work disscussed the effect of structure of spherulite on properties of pure nylon 6 and Nylon 6/TPAE/Compatibilizer alloy by the experiment of changing the cooling velocity when shaping.First
melts of pure nylon 6 and Nylon 6/TPAE/Compatibilizer alloy were cooled rapidly and slowly on the condition of 4℃ water and 23℃ air respectively.Second
they were made into specimens.Then
specimens were carried on observation of structure of spherulite and dispersioin morphology and analyses of absorbing heat
meanwhile by PLM
SEM and DSC
carried on the experiment of tensile fracture and interface tearing. The results show;(1) Dispersion particles are well-distributed between interface and interior of spherulite or between lameller crystals.(2)The size of spherulit is greatly is greatly different when pure nylong 6 is cooled rapidly in 4℃ water.But that of spherulite is well-distributed when it is cooled slowly in 23℃ air.The comparison of them shows the latter speciment's size of spherulite is large and fracture strength is high
with decreasing deformation and energy of tensile fracture.(3) The size of spherulite is small but differs greatly when Nylon6/TPAE/A8200 alloy was cooled rapidly in 4℃ water
but that of spherulite is large and well-distributed in 23℃ air.The comparison of them shows the latter specimen's size of spherulite is large and fracture strength is high
with increasing the deformation and energy and energy of tensile fracture.(4) On the same cooling condition
the change trend of size of soherulite of pure nylon 6 and nylon 6/TPAE/Compatibilizer alloy is same
but that of properties of tensile freacture is oppsite.This a because slow cooling contributes to not only the formation of large spherulite but also the enhancement of adhesion strength of interface between the dispersed phase TPAE and successive phase nylon 6.On the other hand
the dispersion of tiny TPAE particle in the interface and interior of nylon 6 spherulite strengthens the deformation ability of spherulite
and enhances the strength deformation and energy of tenssile fracture. Pure nylon 6 has not these specific properties.Therefore
though the size of spherulite is one of factors which influence fracture properties of nylon6
the interface of spherulite
non-crystal stucture between lamellar crysrals
voiding of tiny elastic and adhesion strength of phase interface are main factors which influence fracture properties of nylon 6.
结晶速度尼龙-6合金界面强度破坏性能
0
浏览量
7
下载量
1
CSCD
关联资源
相关文章
相关作者
相关机构