4,5-环氧环己烷1,2-二甲酸二缩水甘油酯/m-PDA固化体系的形态结构及动态力学行为

黄吉甫; 张保龙; 王德润; 谭建平; 路延岑; 杨飚; 柳志欣

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4,5-环氧环己烷1,2-二甲酸二缩水甘油酯/m-PDA固化体系的形态结构及动态力学行为

研究简报 | 更新时间：2021-03-19

- 4,5-环氧环己烷1,2-二甲酸二缩水甘油酯/m-PDA固化体系的形态结构及动态力学行为
- NETWORK MORPHOLOGY AND DYNAMIC MECHANICAL BEHAVIOR OF DIGLYCIDYL-4,5-EPOXYCYCLOHEXANE -1, 2-DICARBOXYLATE CURED WITH m-PDA
- 高分子学报 1983年第5期页码：385-388
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- 纸质出版日期：1983-10-20，
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黄吉甫, 张保龙, 王德润, 谭建平, 路延岑, 杨飚, 柳志欣. 4,5-环氧环己烷1,2-二甲酸二缩水甘油酯/m-PDA固化体系的形态结构及动态力学行为[J]. 高分子学报, 1983,(5):385-388.

HUANG Ji-fu, CHANG Bao-long, WANG De-run, Tan Jian-ping, Lu Yan-ling, YANG Biao, LIU Zhi-xin. NETWORK MORPHOLOGY AND DYNAMIC MECHANICAL BEHAVIOR OF DIGLYCIDYL-4,5-EPOXYCYCLOHEXANE -1, 2-DICARBOXYLATE CURED WITH m-PDA[J]. Acta Polymerica Sinica, 1983,(5):385-388.
黄吉甫, 张保龙, 王德润, 谭建平, 路延岑, 杨飚, 柳志欣. 4,5-环氧环己烷1,2-二甲酸二缩水甘油酯/m-PDA固化体系的形态结构及动态力学行为[J]. 高分子学报, 1983,(5):385-388. DOI：

HUANG Ji-fu, CHANG Bao-long, WANG De-run, Tan Jian-ping, Lu Yan-ling, YANG Biao, LIU Zhi-xin. NETWORK MORPHOLOGY AND DYNAMIC MECHANICAL BEHAVIOR OF DIGLYCIDYL-4,5-EPOXYCYCLOHEXANE -1, 2-DICARBOXYLATE CURED WITH m-PDA[J]. Acta Polymerica Sinica, 1983,(5):385-388. DOI：

摘要

Abstract

An investigation was conducted on the morphology of diglycidyl-4.5-epoxycyclohexane -1

2-dicarboxylare with emphasis on the effect of curing temperature. A heterogeneous two phase network structure was observed on the etched surfaces of all the samples cured at different temperatures. The sample cured at 110℃ showed the most pronounced inbomogenei ty under SEM and has two peaks in the broad damping curve

whereas the degree of in homogeneity tended to decrease again as the curing temperature was further raised. The re-sults obtained has been interpreted in termsof the specific suring process arising from the unequal activity of epoxide rings on the same molecules.

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