α－蒎烯选择性二聚合及低聚反应研究　Ⅰ．不同催化剂体系的聚合行为和产物构成

邓云祥; 王玉平; 王力昌; 马卿云; 东村敏延

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α－蒎烯选择性二聚合及低聚反应研究　Ⅰ．不同催化剂体系的聚合行为和产物构成

研究论文 | 更新时间：2021-03-19

- α－蒎烯选择性二聚合及低聚反应研究　Ⅰ．不同催化剂体系的聚合行为和产物构成
- STUDIES ON SELECTIVE DIMERIZATION AND OLIGOMERIZATION OF α-PINENEⅠ.ACTION OF VARIOUS CATALYSTS AND THE COMPONENT OF POLYMERIZATION PRODUCTS
- 高分子学报 1995年第1期页码：76-81
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- 纸质出版日期：1995-2-20，
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邓云祥, 王玉平, 王力昌, 马卿云, 东村敏延. α－蒎烯选择性二聚合及低聚反应研究　Ⅰ．不同催化剂体系的聚合行为和产物构成[J]. 高分子学报, 1995,(1):76-81.

DENG Yun-xiang, WANG Yu-ping, WANG Li-chang, MA Qing-yun, Higashlmura T. STUDIES ON SELECTIVE DIMERIZATION AND OLIGOMERIZATION OF α-PINENEⅠ.ACTION OF VARIOUS CATALYSTS AND THE COMPONENT OF POLYMERIZATION PRODUCTS[J]. Acta Polymerica Sinica, 1995,(1):76-81.
邓云祥, 王玉平, 王力昌, 马卿云, 东村敏延. α－蒎烯选择性二聚合及低聚反应研究　Ⅰ．不同催化剂体系的聚合行为和产物构成[J]. 高分子学报, 1995,(1):76-81. DOI：

DENG Yun-xiang, WANG Yu-ping, WANG Li-chang, MA Qing-yun, Higashlmura T. STUDIES ON SELECTIVE DIMERIZATION AND OLIGOMERIZATION OF α-PINENEⅠ.ACTION OF VARIOUS CATALYSTS AND THE COMPONENT OF POLYMERIZATION PRODUCTS[J]. Acta Polymerica Sinica, 1995,(1):76-81. DOI：

摘要

从聚合动力学、异构化和产物构成等方面检讨了质子酸、Ｌｅｗｉｓ酸和质子酸／Ｌｅｗｉｓ酸复合酸三类、多种催化剂和各种反应条件对。α－蒎烯的二聚合及低聚反应的影响．结果表明，活性种为质子Ｈ＋的这三类催化剂主要生成二、三、四聚体产物．发现质子酸与Ｌｅｉｗｓ酸组成的复合催化剂比它们单独时聚会活性大幅度提高，异构化作用显著减少，可以高选择性地合成二聚体．如复合催化剂ＡｌＣｌ３／ＣＦ３ＣＯＯＨ异构化率仅０．５％；聚合收率和二聚体含量分别达到９９．５％和８３．４％．

Abstract

he oligomerlzatlon of α-Pinene initiated by Protonic acids

Lewis acids and compound catalysts of vrotonic acids/Lewis acids underlvarlous conditions were discussed in terms of polymerlzation kinetics

isomerization andproduct's components.The results show that these three types of catalysts with active suedes vroton(H+)produced mainly dimer

trimer and tetramer. The compound catalysts of protonic acids/Lewis acids are more active than either one

and the isomerization ofα-pinene decreased significantly. It is discovered that a dimer could be synthesized selective-ly by the compound catalysts with isomerization ratio only 0.5%. Polymer yield and dimer content 99.5% and 83.4% respectively were obtained by the AlCl3/CF3CO-OH.

关键词

α－蒎烯选择性二聚合α－蒎颁烯低聚反应α－蒎烯聚合

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