FANG Pei-ji, SHI Yan-zhi, WANG Er-jian. STUDY ON THE PHOTOPOLYMERIZATION IN MICELLE SYSTEM Ⅵ. The Photosensitive Polymerization in Water-soluble Macromolecule/Surfactant Complex Systems[J]. Acta Polymerica Sinica, 1995,(6):713-719.
FANG Pei-ji, SHI Yan-zhi, WANG Er-jian. STUDY ON THE PHOTOPOLYMERIZATION IN MICELLE SYSTEM Ⅵ. The Photosensitive Polymerization in Water-soluble Macromolecule/Surfactant Complex Systems[J]. Acta Polymerica Sinica, 1995,(6):713-719.DOI:
he photosensitive polymerization in the types of complex systems comports of water-soluble (PAA-AM) and surfactants (CTAB
SDS
Triton X-100) was studied in this paper. The aggregation process and microenvironmental propelles of these complex systems were monitored by fluorescence probe pyrene. Compared with micelle
the molecular aggregation complex systems showed stronger aggregation ability
better stability
greater local viscosity and polarity
therefore a powerful catalytic effidency on photopolymerization of MMA initiated by benzophenone/triethyl amine was obtaied in these complex systems.