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纸质出版日期:1965-6-20,
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胡又牧, 黄永炎. 天然胶乳离子沉积过程中若干因素的研究[J]. 高分子学报, 1965,7(3):160-170.
HU You-Mo, HUANG YONG-YAN. A STUDY OF THE EFFECT OF SOME FACTORS ON THE IONIC DEPOSITION OF NATURAL RUBBER LATEX[J]. Acta Polymerica Sinica, 1965,7(3):160-170.
本文研究了凝固剂的种类和浓度等因素对天然胶乳离子沉积过程的影响。就沉积能 力而言氯化钙>硝酸钙>醋酸钙>氯化钡>醋酸钡。其中以醋酸钡的凝胶及胶膜性能较好
其他几种凝固剂之间差异不大。钙盐对胶膜老化的影响大于钡盐
其中尤以氯化物为甚。 随着凝固剂浓度的增加橡胶沉积量、凝胶起始浓度及凝胶物理性能均增加。但当使用氯化钙时
在15%左右凝胶抗张力达到最大。 在沉积过程中凝胶浓度起始稍高
随后逐渐下降至一定程度后又缓慢上升
凝胶性能也有类似的变化。 沉积方法与凝固剂的附型剂对沉积过程有明显影响。 由以上结果:我们认为天然胶乳的离子沉积过程可以分成三个阶段:(a)凝结、(b)过渡、(c)胶凝。由以上试验数据证明了所提出的离子沉积动力方程式基本上是正确的。但整个离子沉积过程用q=q_0(kt)/(1+kt)来表示
可能要更好一些。
A study has been made of the influences of some factors (types and concentration of coagulants,etc) upon the ionic deposition of natural rubber latex with coagulants.It was found that the rate of deposition varied with the types of coagulants,in the order of calcium chloride>calcium nitrate>calcium acetate>barium chloride>barium acetate.The mechanical properties of wet-·gel and dry-film with barium acetate were quite good.The ageing characteristics of dry—film deposited with calcium salts were poorer than that with barium salts.especially for the chlorides.The amount of ionic deposition,the initial concentration of wet—gel,and the mechani-cal properties of wet-gel increased with the concentration of coagulant. But when cal-cium chloride was used,the mechanical properties of wet-gel attained a maximum at a concentration of 15%.During the ionic deposition,the concentration of wet-gel was found to decrease at first and then a slight increase after the minimum value was reached.The properties of wet-gel underwent similar changes.Both the deposition method and the carrier of coagulant had pronounced effects upon ionic deposition.According to the above results.the ionic deposition of natural rubber latex can be considered to be proceeding in three stages:(a)coagulation;(b)the transition stage;(C)gelation.From the experimental data,we are able to prove that the Sandomirskii’s kinetic equation of ionic deposition is a reasonable one;but it is probably better to express the whole course of ionic deposition by an empirical equation of the type.
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