甲基丙烯酸甲酯与甲基丙烯酸异丁酯或丙烯酸酯类的乳液共聚合及其共聚物热裂解的研究

陈镜泓; 李基森; 包华清; 朱关根

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甲基丙烯酸甲酯与甲基丙烯酸异丁酯或丙烯酸酯类的乳液共聚合及其共聚物热裂解的研究

研究简报 | 更新时间：2021-03-19

- 甲基丙烯酸甲酯与甲基丙烯酸异丁酯或丙烯酸酯类的乳液共聚合及其共聚物热裂解的研究
- STUDIES ON THE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE WITH ISOBUTYL METHACRYLATE OR ACRYLATES AND THE DEGRADATIONS OF THESE COPOLYMERS
- 高分子学报 1982年第4期页码：306-309
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- 纸质出版日期：1982-8-20，
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陈镜泓, 李基森, 包华清, 朱关根. 甲基丙烯酸甲酯与甲基丙烯酸异丁酯或丙烯酸酯类的乳液共聚合及其共聚物热裂解的研究[J]. 高分子学报, 1982,(4):306-309.

Chen Jing-hong, Li Ji-sen, Bao Hua-qing, Zhu Guang-en. STUDIES ON THE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE WITH ISOBUTYL METHACRYLATE OR ACRYLATES AND THE DEGRADATIONS OF THESE COPOLYMERS[J]. Acta Polymerica Sinica, 1982,(4):306-309.
陈镜泓, 李基森, 包华清, 朱关根. 甲基丙烯酸甲酯与甲基丙烯酸异丁酯或丙烯酸酯类的乳液共聚合及其共聚物热裂解的研究[J]. 高分子学报, 1982,(4):306-309. DOI：

Chen Jing-hong, Li Ji-sen, Bao Hua-qing, Zhu Guang-en. STUDIES ON THE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE WITH ISOBUTYL METHACRYLATE OR ACRYLATES AND THE DEGRADATIONS OF THESE COPOLYMERS[J]. Acta Polymerica Sinica, 1982,(4):306-309. DOI：

摘要

Abstract

Three kinds of copolymeric emulsions with concentrations up to the extent of 40 per cent were prepared by using a mixed emulsion system of ionic and nonionic emul-sifying agent in emulsion qopolymerization．Copolymeric emuLsiOIlS which had been ireated with cation and anion exchange resins are stable to long-time storage and their residual substance is eomparalble to a standard of nonionie emulsion．TG，DTG. GC-MS and pyrolysis gas chromatographic methods were used to determine the influence of variOUS copolymers．as well as the ratio of its components towards degradation rate．An order of susceptibility of degradation of these copolymers was found．These results may be of a help to finding way for synthesizing of barrier filming materials for color picture tube in aluminized screen techniques．

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