STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers
LI Fu-mian, WANG Lin, DING Yi-wei, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers[J]. Acta Polymerica Sinica, 1985,(4):316-320.
LI Fu-mian, WANG Lin, DING Yi-wei, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP Ⅷ. Synthesis and Polymerization of N-aerylyl-N'-methyl-Piperazine, and the Antithrombogenecity of its Polymers[J]. Acta Polymerica Sinica, 1985,(4):316-320.DOI:
Aliphatie tertiary amino-group N-substituted aerylamides.N-acrylyLN’-methylpipe-rasine (AMP) and N-methaerylyl-N'-methyl piperazine(MAMP) were synthesized dire-ctly.from N-methylpiperasine with corresponding acryl chlorides and characterized bly the elementary analysis of their picrates,1H-NMR
IRand MS. AMP did not poly-merize with benzoyl peroxide.but could polymerize with LPO.The rate equation of the polymerization was given as Rp=Kp [AMP]0.5 [LPO]0.5 and the overall activation energy of this polymerization system was determined as low as 10.8 keal/mol.The redox nature of LPO with the monomer itself had been suggested.The polymers of these N-substituted aerylamides display good antithrombogeneeity tested by reaeleifieation me-thod.