QIU Kun-yuan, Zhang Jing-yi, FENG Xin-de. THE EFFECT OF AMINE ON THE RADICAL POLYMERIZATION INITIATED WITH ORGANIC PEROXIDES[J]. Acta Polymerica Sinica, 1984,(1):77-80.
QIU Kun-yuan, Zhang Jing-yi, FENG Xin-de. THE EFFECT OF AMINE ON THE RADICAL POLYMERIZATION INITIATED WITH ORGANIC PEROXIDES[J]. Acta Polymerica Sinica, 1984,(1):77-80.DOI:
the radical polymerization of methyl methacrylate (MMA) initiated with benzoyl peroxide (BPO)
lauroyl peroxide (LPO)
t-butyl hydroperoxide (TBH)
t-butyl peroxybenzoate (TBPB) and the effect of amine on the radical polymerization rate were studied
respectively. It was found that the order of polymerization rate Rp was as follows: LPO > BPO > TBH > TBPB. In the presence of tertiary amine such as N
N-di-methyl-p-toluidine (DMT)
N-ethyl piperidine (NEP)
the amine promoted the polymerizatio of MMA
and the order of Rp changed to BPO-amine>LPO-amine>TBH-amine>TBPB-amine.