FAN Qing-rong, XU Duan-fu, ZHAO De-lu, QIAN Ren-yuan. EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER[J]. Acta Polymerica Sinica, 1984,(1):62-68.
FAN Qing-rong, XU Duan-fu, ZHAO De-lu, QIAN Ren-yuan. EFFECT OF MOLECULAR WEIGHT DISTRIBUTION ON THETEXTURE FORMATION OF AS-SPUN ISOTATICPOLYPROPYLENE FIBER[J]. Acta Polymerica Sinica, 1984,(1):62-68.DOI:
The effects of toolecular weight distribution on the texture formation of as.spun fibe-rs and mechanical properties of polypropylene fibers have been studied.It is shown that the texture formation of as-spun fibers is very sensitive to the presence of high molecalar wei-ght tail in the MWD of polypropylene resin.Under ordinary spinning conditions the as-spun fiber obtained from controHed degraded polypropylene resin showed smectic structu-re with low degree of oritation.However,in the presence of some high molecular weight tail incorproated to the degraded polypropylene resin gave as-spun fibers in a-crystalline modi-fication,although the viscosity average molecular weight and spinning conditions were kept the same.In addition,the birefringence of the as-spun fibers increased sharphy with increa-sing amocnt of the high molecular weight tail in the MWP.The different texture of as-spun fibers resulted in big difference in stretching behavior of the as-spun fiber and mechanical properties of drawn fibers.