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纸质出版日期:1979-4-20,
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张兴华, 鲁雁英, 杨亚君, 王天用, 刘香鸾, 朴爱植, 贝建中, 陈步时. 用于递模塑料的有机硅树脂[J]. 高分子学报, 1979,(2):74-83.
Chang Hsing-hua, Lu Yen-ying, Yang Ya-chun, Wang Tien-yung, Liu Hsiang-luan, Piao Ai-chih, Pei Kien-chung, Che Pu-shih. ORGANOSILICON RESINS FOR TRANSFER MOULDING COMPOUNDS[J]. Acta Polymerica Sinica, 1979,(2):74-83.
张兴华, 鲁雁英, 杨亚君, 王天用, 刘香鸾, 朴爱植, 贝建中, 陈步时. 用于递模塑料的有机硅树脂[J]. 高分子学报, 1979,(2):74-83. DOI:
Chang Hsing-hua, Lu Yen-ying, Yang Ya-chun, Wang Tien-yung, Liu Hsiang-luan, Piao Ai-chih, Pei Kien-chung, Che Pu-shih. ORGANOSILICON RESINS FOR TRANSFER MOULDING COMPOUNDS[J]. Acta Polymerica Sinica, 1979,(2):74-83. DOI:
本文指出提高水解温度
或使用丙酮和甲苯混合溶剂
有利于甲基三氟硅烷与苯基三氯硅烷和二甲基二氯硅烷的共水解缩聚反应
而不易产生凝胶现象。并以此合成了适于递模塑料的R/Si较小、C6H5/R较低、羟基含量较高的羟基缩合型无溶剂树脂
简化了步骤
大大缩短了操作时间
树脂质量稳定。此外还讨论了树脂的结构与递模塑料性能的关系
选择了较好的固化剂以及通用的补强剂
使塑料具有优异的性能。
It has been shown that increasing the temperature of hydrolysis or using a mixed solvent composed of acetone and toluene favours the hydrolytic co-condensation of me-thyltrichlorosilane with phenyltrichlorosilane and dimethyldichloroaihme,but avoids the gel-forming phenomenon.As a result of which a solventless
hydroxyl condensativn type silicone resins with lower R/Si,C6H5/R ratio and higher Si-OH group content can be prepared,and the resins are suitable for transfer moulding compounds.By umng these methods the probedure is simplified,the time of operation is greatly shortened and the quality of the resins is stable.In addition.the relation between the structures of the resins and the properties of the transfer moulding plastics has been discussed.A proper choice of curing agent and a general purpose reinfereed filler will result in excellent performance of the plasties.
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