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纸质出版日期:1966-12-20,
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何炳林, 刘操. 高强度强碱性阴离子交换树脂的研究[J]. 高分子学报, 1978,(2):103-109.
Ho Ping-lin, Liu Tsao. A RESEARCH ON THE HIGH IMPACT STRENGTHANION EXCHANGERS WITH STRONG-BASEQUATERNARY AMMONIUM GROUPS[J]. Acta Polymerica Sinica, 1978,(2):103-109.
本文用橡胶-苯乙烯-二乙烯基苯合成了接枝共聚体
用石油醚和丁酮
甲醇混合液在 Soxhlet提取器上对共聚体实行提取以后
进行了氯甲基化与铵化
实验证明
制得的新树脂具有明显的弹性
韧性和良好的耐压性质
普通的凝胶型树脂很脆
当形变10%时开始破碎
耐压只有200—300克
而新树脂形变可达20%以上而不破坏
耐压可达700克
本文同时对新树脂的含水量
密度
交换速度也进行了研究。
After the graft eopolymer of styrene-divinyl benzene.rubber had been extracted first with petroleum ether and then with a mixture of methyl ethyl ketone and me-thanol in the soxhlet extractor in order to get rid of the linear polymer,the degree of unsaturation was determined.From the experimental results.it was shown that the degree of unsaturation in the graft eopolymer of S-DVB-R was not decreased.The graft eopolymer which,having been extracted,possesses higher swelling eoef-ficient tjlan that of the eopolymer of S-DVB Was ehlVromethylated and amlnated by the ordinary method. It was discovered that it tovk a longer time for the ehlorome.thylation of copolymer containing rubber than that,it did nbt contain any.The pro-duct thus obtained was tested for meehanical strength under wet condition.it was found that the gran
ular particles with an average diameter of 0.64 mm were not bro-ken until an average weight of 700 g was added on.They also had a better elasticdty
and tenaeity.By the indica
tvr method,the exchange velocity of the ffewly prepared resin was ditermined with hydrochloric acid.The diffusion coefficient was calculated according to the method adopted by Reiehenbery.The result showed that the new resin posses.ses la.higher diffusion eoefficient.The new resin also possesses higher water content and lower density than those of the vrdinary resin.
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