8-丙烯酰氧喹啉及其聚合物增感的丙烯腈光聚合

张举贤; 高青雨; 陈双基; 李福绵

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8-丙烯酰氧喹啉及其聚合物增感的丙烯腈光聚合

研究简报 | 更新时间：2021-03-19

- 8-丙烯酰氧喹啉及其聚合物增感的丙烯腈光聚合
- PHOTOPOLYMERIZATION OF ACRYLONITRILE SENSITIZED BY 8-ACRYLOYLOXYQUINOLINE AND ITS POLYMER
- 高分子学报 1990年第2期页码：249-252
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- 纸质出版日期：1990-4-20，
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张举贤, 高青雨, 陈双基, 李福绵. 8-丙烯酰氧喹啉及其聚合物增感的丙烯腈光聚合[J]. 高分子学报, 1990,(2):249-252.

ZHANG Ju-xian, GAO Qing-yu, CHEN Shuang-ji, LI Fu-mian. PHOTOPOLYMERIZATION OF ACRYLONITRILE SENSITIZED BY 8-ACRYLOYLOXYQUINOLINE AND ITS POLYMER[J]. Acta Polymerica Sinica, 1990,(2):249-252.
张举贤, 高青雨, 陈双基, 李福绵. 8-丙烯酰氧喹啉及其聚合物增感的丙烯腈光聚合[J]. 高分子学报, 1990,(2):249-252. DOI：

ZHANG Ju-xian, GAO Qing-yu, CHEN Shuang-ji, LI Fu-mian. PHOTOPOLYMERIZATION OF ACRYLONITRILE SENSITIZED BY 8-ACRYLOYLOXYQUINOLINE AND ITS POLYMER[J]. Acta Polymerica Sinica, 1990,(2):249-252. DOI：

摘要

Abstract

The photopolymerization of acrylonitrile (AN) was studied by using 8-acryloyloxyquino-line (AQ) and its polymer (PAQ) as sensitizers under UV irradiation. The photopolymerization rate of AN in DMF by using AQ as sensitizer is proportional to 0.36th power of AQ concentration and 1.10th power of AN concentration. In the case of PAQ as sensitizer for the photopolymerization of AN

the rate is proportional to 0.31th power of PAQ concentration and 0.73 th power of AN concentration. From the recording of fluorescence intensity of PAN sensitized by AQ and PAQ

it is confirmed that AQ and PAQ not only sensitized the photopolymerization of AN but also entered into the PAN chains. The initiation mechanism was tantatively deduced.

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8-丙烯酰氧喹啉丙烯腈光聚合

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