QIU Xing-yu, LI Guan-jun, PING Xue-zhen. STUDIES ON THE THERMAL DECOMPOSITION OF HYDROGEN PEROXIDE AND INITIATED ACRYLONITRILE POLYMERIZATION[J]. Acta Polymerica Sinica, 1990,(2):162-167.
QIU Xing-yu, LI Guan-jun, PING Xue-zhen. STUDIES ON THE THERMAL DECOMPOSITION OF HYDROGEN PEROXIDE AND INITIATED ACRYLONITRILE POLYMERIZATION[J]. Acta Polymerica Sinica, 1990,(2):162-167.DOI:
The thermal decomposition of hydrogen peroxide in DMF and the polymerization of acry-lonitrile initiated by hydrogen peroxide were studied. The rate constants and activation energy of thermal decomposition of hydrogen peroxide in DMF were determined. And from the kinetic data measurments of the polymerization of acrylonitrile in DMF at 105℃
the polymerization rate equation of acrylonitrile was presented as Rp=K[H2O2]0.39[AN]1.85.