SHEN Jing-shu, WANG Tian-gui, QI Zong-neng, Qian Ken-yuan. CORRELATION BETWEEN a-RELAXATION AND OTHERMECHANICAL BEHAVIORS OF UNIAXIALORIENTED PET FILMS[J]. Acta Polymerica Sinica, 1981,(2):81-87.
SHEN Jing-shu, WANG Tian-gui, QI Zong-neng, Qian Ken-yuan. CORRELATION BETWEEN a-RELAXATION AND OTHERMECHANICAL BEHAVIORS OF UNIAXIALORIENTED PET FILMS[J]. Acta Polymerica Sinica, 1981,(2):81-87.DOI:
In this paper,we use the α-relaxation in dynamic mechanical behavior of poly (ethylene terephthalate (PET) as a probe,to detect the difference in the state of mole-eular aggregation of PET in the amorphous region under various conditions of draw-ing.Our studies show that,the quite different state of the amorphous regions of ori-ented PET samples can be obtained by variation of the speed and temperature of drawing,and the state of their amorphous regions is clearly demonstrated to be different by their a-peaks.Because the position,height and shape Df the a-peak in mechanical-10ss(Tan δ)-temperature curve reflect the intermolecular interactions and hence the state of the amorphous region of oriented PET sample,so that,those parameters show rea-sonable correlation with other mechanical behaviors and gome structure parameters of the PET sample.Furthermore,the experimental results show that there is an Arrhenius type equiva-lence between the draw speeds and the draw temperatures of samples with similar amorphous state.