XIONG Jing, ZHANG Yu-xi, ZHAO Xiao-jiang, WANG Fo-song. IONIC CONDUCTIVITY IN THE COMPLEX OF TERNARY POLYMER P(EO-PO-AGE) AND LiClO4[J]. Acta Polymerica Sinica, 1991,(1):7-11.
XIONG Jing, ZHANG Yu-xi, ZHAO Xiao-jiang, WANG Fo-song. IONIC CONDUCTIVITY IN THE COMPLEX OF TERNARY POLYMER P(EO-PO-AGE) AND LiClO4[J]. Acta Polymerica Sinica, 1991,(1):7-11.DOI:
Poly (ethylene oxide-propylene oxide-allyl glycidyl ether) was prepared
and it shows a low glass transition temperature (Tg=-74℃) and a high amorphous ratio (98%). DSC and X-ray diffraction measurements were employed to characterize the P(EO-PO-AGE)-LiClO4 complex morphology
a crystall complex with the composition of Li/O=0.25 was detected. The studies on ionic conductivities of complexes found that the conductivities change with the salt concentration
and reached a maximum of 5×10-5scm-1 at room temperature with Li/O=0.05.