LU FENG-CAI, XING Lan-min, Wang Yu-lan, Liu Yu. SYNTHESIS OF POLYPHENYL-AS-TRIAZINE FROM 1,4-DICYANOBENZENE[J]. Acta Polymerica Sinica, 1980,(4):193-197.
LU FENG-CAI, XING Lan-min, Wang Yu-lan, Liu Yu. SYNTHESIS OF POLYPHENYL-AS-TRIAZINE FROM 1,4-DICYANOBENZENE[J]. Acta Polymerica Sinica, 1980,(4):193-197.DOI:
A relatively high molecular weight polyphenyl-as-triazine (PPT) was preparedfrom two monomers--terephthalamidrazone and 1
4-bis (phenylglyoxaloyl) benzene.ηinh was equal to 1.93 dl/g (0.5% in eresol at 25℃) and T
was 320℃ as determined by differential thermal analysis (DTA).This polymer film exhibited good thermally oxidative stability and it's tensile strength at room temperature was higher than 1000 kg/em2. When the film was treated in boiling water for 200 hours
it retained good insulation (30-35 μ
1010Ω)and flexibility
and no change was observed in it's IR spectrum. The PPT film showed no loss in weight after being treated for 30 hours at 200℃ in water.