甲基苯基次膦酸与锌盐的水溶液配位聚合及聚合物水溶液的电导行为

刘汉范; 郭传杰; 李贞宜; 刘淑芬

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甲基苯基次膦酸与锌盐的水溶液配位聚合及聚合物水溶液的电导行为

研究论文 | 更新时间：2021-03-19

- 甲基苯基次膦酸与锌盐的水溶液配位聚合及聚合物水溶液的电导行为
- POLYMERIZATION OF METHYLPHENYLPHOSPHINIC ACID WITH ZINC SALTS AND BEHAVIOR OF ZINC METHYL-PHENYLPHOSPHINATE IN AQUEOUS MEDIA
- 高分子学报 1981年第6期页码：468-471
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- 纸质出版日期：1981-12-20，
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刘汉范, 郭传杰, 李贞宜, 刘淑芬. 甲基苯基次膦酸与锌盐的水溶液配位聚合及聚合物水溶液的电导行为[J]. 高分子学报, 1981,(6):468-471.

LIU Han-fan, Guo Chnan-jie, Li Zhen-yi, Liu Shu-fen. POLYMERIZATION OF METHYLPHENYLPHOSPHINIC ACID WITH ZINC SALTS AND BEHAVIOR OF ZINC METHYL-PHENYLPHOSPHINATE IN AQUEOUS MEDIA[J]. Acta Polymerica Sinica, 1981,(6):468-471.
刘汉范, 郭传杰, 李贞宜, 刘淑芬. 甲基苯基次膦酸与锌盐的水溶液配位聚合及聚合物水溶液的电导行为[J]. 高分子学报, 1981,(6):468-471. DOI：

LIU Han-fan, Guo Chnan-jie, Li Zhen-yi, Liu Shu-fen. POLYMERIZATION OF METHYLPHENYLPHOSPHINIC ACID WITH ZINC SALTS AND BEHAVIOR OF ZINC METHYL-PHENYLPHOSPHINATE IN AQUEOUS MEDIA[J]. Acta Polymerica Sinica, 1981,(6):468-471. DOI：

摘要

Abstract

Polymerization of methylphenylphosphinic acid with zinc oxide has been investigated in aqueous media. Two species of polymer were obtained at the same time. One is crystalline

the other membranous (amorphous).They are allotropes. Using Onsager's equation

it has been shown that the soluble part of the polymer are in the form of ionic Zn++

MePhPO2- in aqueous solution

and so hydrolysis of this kind of polymers seems to be the process of dissolution and recrystallization in aqua.

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